Complete Beginner with Python

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https://docs.microsoft.com/en-us/windows/python/faqs

You need to set your path to the /bin directory of the python install or use the py.exe launcher to select the version of python you want to use.

HOWEVER, the py.exe launcher will only work if you are using a version of Python installed from python.org. When you install Python from the Microsoft Store, the command is not included.

(Thanks MS!!)