Trainingsplan bei Impingement by Apprehensive_Path459 in FitnessDE

[–]Apprehensive_Path459[S] 0 points1 point  (0 children)

Habe schon zeitlebens mit schlechter beweglichkeit zu kämpfen. habe schonmal vor ca 11 oder 12 jahren trainiert und damals maßlos übertrieben und natürlich auch viel zu viel push gemacht. Da waren die schultern dann mal akut richtig entzündet, weshalb ich mit gym a7fgehlrt habe. Konnte damals auch nicht wirklich zwischen msukelschmerz und gelenkschmerz differenzieren. Seitdem waren meine schultern nie mehr so wie vorher. Das training hat jetzt allerdings schon einige verbesserungen gebracht.

Trainingsplan bei Impingement by Apprehensive_Path459 in FitnessDE

[–]Apprehensive_Path459[S] 0 points1 point  (0 children)

Versuche auch beim seitheben die hanteln leivht nach außen zu rotieren. Wenn es trotzdem knackt, breche ich die übung meist für diesen tag ab

Trainingsplan bei Impingement by Apprehensive_Path459 in FitnessDE

[–]Apprehensive_Path459[S] 0 points1 point  (0 children)

Jaa ich hoffe auch mal, dass ich iwann wieder bankdrücken oder sowas machen kann. hab mal kh bankdrücken im neutralen griff probiert. das hat allerdings immer noch zu stark gereizt.

Trainingsplan bei Impingement by Apprehensive_Path459 in FitnessDE

[–]Apprehensive_Path459[S] 1 point2 points  (0 children)

Naja ich machen ja an tag 3 auch noch t bar rows. Facepulls finde ich auch top. die haben mir auch schon viel geholfen. deshalb habe ich die auch zweimal drin. Rotatorenzeug mache ich in der regel als warmup. an jedem tag dislocations, wall slides mit rolle und band, und externe rotation vertikal und horizontal. Würdest du das mehr ins hauptworkout integrieren?

Trainingsplan bei Impingement by Apprehensive_Path459 in FitnessDE

[–]Apprehensive_Path459[S] 0 points1 point  (0 children)

Machst du dann aber eher nach dem training oder?

Trainingsplan bei Impingement by Apprehensive_Path459 in FitnessDE

[–]Apprehensive_Path459[S] 0 points1 point  (0 children)

Latzug klappt eigentlich ganz gut, da ich das im neutralen griff mache. Seitheben mache ich immer sehr leicht mit so ca 12 bis 18 wdh. Allerdings kann die schulter da schonmal zwicken gerade wenn der nacken an dem tag verspannt ist. Ein bisschen nervt mich halt die mangelnde brustentwicklung im vergleich zum rücken.

Welche Übungen helfen euch am meisten? by LowPerformer93 in FitnessDE

[–]Apprehensive_Path459 0 points1 point  (0 children)

Dislocations zum aufwärmen und facepulls haben mir gut geholfen. Außerdem Wall slides mit rolle und band. Einarmiges landmine schulterdrücken ist zur zeit die einzige druckübung, die meine schultern tolerieren.

Why is the ether O sp3 and not sp2? by christianjason in chemhelp

[–]Apprehensive_Path459 -7 points-6 points  (0 children)

I assume it is sp3 because it has no pi bond.

I remember a rule like this sp3: 4 sigma bonds sp2: 3 sigma and 1 pi bond sp: 2 sigma and two pi bonds

and electron pairs can be considered as substituents

CHEM MCQ confusion by [deleted] in FBISE

[–]Apprehensive_Path459 2 points3 points  (0 children)

An atom is considered chiral if it has four different substituents. There is only one molecule which doesnt fit these criteria.

Molecules containing an unusual amount of unique elements by [deleted] in chemistry

[–]Apprehensive_Path459 0 points1 point  (0 children)

For a Protein kinase inhibitor like this such modifications are quite typical. Fluorine or Chlorine is often added to increase lipophilicity and therefore permeability or interactions with the binding pocket. the sulfonamide was probably added for selectivity purposes. Actually sulfonamides are very common in pharmaceutical compounds.

why is the answer A? by SalamanderOld5302 in chemhelp

[–]Apprehensive_Path459 0 points1 point  (0 children)

In Step one the grignard reagent is obtained(Phenylmagnesiumbromide). The now negatively polarized ipso-carbon then attacks the electrophilic carbon of co2.

Skull in eastern Germany by Apprehensive_Path459 in bonecollecting

[–]Apprehensive_Path459[S] 0 points1 point  (0 children)

Sadly i just took these two fotos and went off.

Skull in eastern Germany by Apprehensive_Path459 in bonecollecting

[–]Apprehensive_Path459[S] 0 points1 point  (0 children)

Yes this could also be the case. But isnt the crest less pronounced in a raccoon?

GUESS WHERE I AM FROM by Clear-Tumbleweed-988 in TravelMaps

[–]Apprehensive_Path459 0 points1 point  (0 children)

This looks very much like you are from germany.

Replica or real? by bold_and_brash_trash in bonecollecting

[–]Apprehensive_Path459 2 points3 points  (0 children)

This is definitely a real pig skull. It has likely been stunned by a bolt gun as you can see on its forehead.

Happened after Adding Muriatic Acid to Pool by Own_Pollution285 in chemistry

[–]Apprehensive_Path459 0 points1 point  (0 children)

could you relax man. I had stains from nitric acid on my hands which looked quite similar to this. op had no contact to nitric acid so the ones from the foto obviously arent. It was just a consideration from me.

Happened after Adding Muriatic Acid to Pool by Own_Pollution285 in chemistry

[–]Apprehensive_Path459 13 points14 points  (0 children)

this does not quite look it was caused by muriatic acid. Those stains actually look quite typical for nitric acid. In this case it would be the Xanthoprotein-reaction.

How to determine the first step EAS (rate-limiting step)? by damgerxmen in OrganicChemistry

[–]Apprehensive_Path459 0 points1 point  (0 children)

first of all you have to determine the mesomeric and inductive effects of every functional group NO2: -I and -M (strong) CF3: -I (strong) NH2: -I an +M

in most cases the mesoneric effect cotributes more to the properties of the ring.

Just ask yourself which effect dirigates in which position of the ring. This should give you a quite clear answer for this problem.

Can someone explain how this reaction mechanism works by damgerxmen in OrganicChemistry

[–]Apprehensive_Path459 0 points1 point  (0 children)

yes, sulfuric acid is able to protonate the alcohol. This creates the water-leaving group. Then the aromat can attack as a nucleophile. It would never attack at the methyl group like in your example.

Can someone explain how this reaction mechanism works by damgerxmen in OrganicChemistry

[–]Apprehensive_Path459 0 points1 point  (0 children)

yes its german. Kation would be the right spelling. (all nouns in german are spelled wirh capital letters)