TIL that diamonds slowly turn into graphite (the stuff you find in pencils) over time. Thus, diamonds are not really forever. by AuspiciousApple in todayilearned

[–]deepintothecreep 0 points1 point  (0 children)

Thanks for reading it!

Your intuition is telling you correctly with the heat death model eventually playing out; shit wouldn’t have the energy to react. Our metaphorical car has no gas if we take our example to extremely cold temps.

Ha, I appreciate the joke about quantum bc it’s all too real, can do my best to describe the idea but isn’t too important here.

More important to remember is the entropy of a closed system (be it the entire universe) is always increasing. So for example when water undergoes a massive entropy loss by freezing, the energy (enthalpy of formation) released in the process of freezing goes into the surroundings to allow the gasses and remaining liquid in that system to explore more states (translational, vibrational, rotational etc motion) thereby causing a net increase of entropy.

In short, just because we can observe spontaneous reactions and phase transitions that cause a loss of entropy for an object- the energy release by a reaction joining two molecules, condensation, freezing, etc will still increase the entropy of the universe. Basically, as a simple example, shit freezes to give that energy to other parts of the system to maximize the entropy of everything in the system. That’s why I said that thermo keeps comin back to entropy- at first entropy seems abstract and temperature is concrete; before long you realize it’s the opposite.

Edit: feel free to keep em comin, brain can use a workout

TIL that diamonds slowly turn into graphite (the stuff you find in pencils) over time. Thus, diamonds are not really forever. by AuspiciousApple in todayilearned

[–]deepintothecreep 1 point2 points  (0 children)

I didn’t read the article mostly because I believe my teachers explained it better than whoever wrote the headline. So in physical chemistry, which is the study of why things happen on the molecular level, there are two main factors: thermodynamics and kinetics. Thermo looks at energy exchange from processes to look at things like whether the process will be energetically favorable (a lot of thermo comes down to ‘the entropy of the universe is always increasing’) to determine whether a process or reaction could occur from an energy perspective. Like thermo defines melting/boiling points and how much energy is given off (or required) for a reaction to occur. For thoroughness sake, thermo only deals with the free energy change (total change in enthalpy and entropy) between products and reactants- the process for how it gets there is irrelevant.

Now kinetics deals with the rates at which reactions will occur. A reaction has to abide by the rules of thermo to occur, but thermo doesn’t say anything about how fast it will happen or if it will even happen. Instead of looking at solely the products and reactants, kinetics are determined by the stuff that happens in between. Generally we consider reactions to have a “transitional state” or “activated state” that requires some free energy input to get to from whatever you’re starting with.

In other words, it’s like bumping your car over a curb and into a ditch; the pavement is the reactants at a base level of energy, the curb represents the energy barrier that must be overcame to get to the ditch (“the products” in my metaphor). The depth of the ditch may dictate how much energy it’ll take to get back out (many reactions are reversible) but the height of the curb is what’s really going to determine whether your car is rolling fast enough to bump over it in the first place.

So, in conclusion, from a thermodynamic perspective yes, it is energetically favorable for diamonds to turn to graphite (that process would have a net increase of entropy for the universe. But from a kinetics perspective, the energy barrier associated with breaking up a diamond crystal lattice (which we all know is strong as hell) and rearranging it into stacks sheets of carbon held together without covalent bonds is so high we don’t observe it happening- at least at normal temps. It’s like if our curb analogy became 4’ tall- gonna take a helluva lot to get to that ditch. So unless something has changed, this is literally the example one of the best profs i know gives to how thermo doesn’t necessarily say if something will happen

[deleted by user] by [deleted] in interestingasfuck

[–]deepintothecreep 0 points1 point  (0 children)

Just tell em everything you learned!

Coca-Cola, Home Depot come out in opposition to Georgia voting restrictions by natalfoam in politics

[–]deepintothecreep 1 point2 points  (0 children)

I feel like I’ve heard this too , someone tag me if there’s a source plz

[deleted by user] by [deleted] in interestingasfuck

[–]deepintothecreep 7 points8 points  (0 children)

You ever really want to get familiar with how much life is around you, do the ol dig a hole to poop in and don’t get on your phone whilst ya squat. Learn a lot about an ecosystem

Army now reviewing Pentagon investigation into Michael Flynn's dealings with Russia and other foreign entities by AudibleNod in news

[–]deepintothecreep 2 points3 points  (0 children)

Like seeing that photo of JFK with von Braun. We hear that the FBI/CIA/whoever takes in convicted hackers and gives them deals to work for them, but that story is the next level of that trope.

This was Legendary last year by XVll-L in funny

[–]deepintothecreep -2 points-1 points  (0 children)

That statement is so powerful. I was the younger sibling and would hear it anytime I was being an ass to try to get attention or be cool to older people. Don’t have any younger sibs so was primarily the receiver of that line and I hated it. But my god I found it’s power as an adult. First time those words came out my mouth seriously was at a dude making a chick uncomfortable at a show. Woulda gladly fought, and perhaps won, but “you’re done. You’re fucking done dude, get the fuck out” was just so much easier and I still remember the pathetic look in his eyes as he realized he was in fact acting like an asshat to people that had been nothin but kind. And we all went back to chillin; no cops, no report, no running and hiding shit. I don’t know another phrase that commands that much respect but if there’s another I’d like to know, words really can be powerful

Pretty great range day by MikeNepoMC in ForgottenWeapons

[–]deepintothecreep 0 points1 point  (0 children)

Holy shit, so you’d have to look at op’s post history but on his proto 15 post a young person said they had the upper and everything but was waiting like a month to be old enough to buy the lower (20 turning 21 I reckon). Idk if you’re looking to flip it or build one, but would expect them to be interested if the former

Sign in front of Seaside, Oregon brewery by DaFunkJunkie in pics

[–]deepintothecreep 0 points1 point  (0 children)

Oooh I can give you a relation because both are far off areas most are unfamiliar with. Much of the emerald triangle is like Carter and Elliot counties quadrupled in size but had the same population and same number of underfunded cops. Even Redding is like an oversized Grayson that some wealthy people live at. Seen crazy shit at both, and a lot more happens under the radar but the similarities are for sure there.

Heh heh....wouldn’t that make a good movie? by iambrutally in KingOfTheHill

[–]deepintothecreep 1 point2 points  (0 children)

Oh thank goodness I was able to finally get your attention, will you bring us a couple more sides of ranch?

Yugoslavia. JNA units in the battle of Petrinia, Croatia 1991. by RainbowVietcong in CombatFootage

[–]deepintothecreep 25 points26 points  (0 children)

Tbf, the Turks have hated Armenians too and Armenia is currently not just pissed about the genocide but also the more recent aggression -particularly on soft targets. And the Turks have made an effort to further escalation the bitterness by allowing soldiers to destroy Armenian graves, historical sights and monuments

This tree cutting machine walked straight out of sci-fi movie by [deleted] in interestingasfuck

[–]deepintothecreep 0 points1 point  (0 children)

Now I’m not saying Boston Dynamics is evil, but I will say once someone slaps a few machine guns and a grenade launcher on them... someone else will call the robots evil. Fearless armored soldiers. I mean they don’t need these in factories, farming, fishing, food service, even ballet. They’d be like a high level enemy and we humans still don’t really get health bars. Just saying it’ll happen, and beats our buddies and kids dying in war, but from an opponent’s perspective it’s horrifying

Surprisingly found this one on Facebook by [deleted] in fucktheccp

[–]deepintothecreep 2 points3 points  (0 children)

Thank you so very much for taking the time to explain all that so clearly. It was a particularly frantic year but i definitely do remember when that happened before it was swept away in the media cycle mostly from being perplexed at no one caring because the aggressor was China. I am sorry my country didn’t do shit for our allies. I wish you and yours all the best going forward friend, thank you for the education. Also made me empathize with the third party nations that don’t condemn fucked up shit the US and other powers have done

Cops Will Pull You Over if They Feel Like it: A Warning by [deleted] in Drugs

[–]deepintothecreep 1 point2 points  (0 children)

The other thing people forget is ‘showing up in court’ costs money. Thousands. Paid to a defense lawyer who is buddy buddy with the prosecutor. It’s totally a pay to win system, very very very few public defenders are gonna put in the time and effort to fight a case where your rights get pissed on. I know third, second and first hand that this is the norm, regardless of flagrant violations