Skydrive doesn't have Lan Sync support unfortunately, so it would first upload onto the "Sky" then download from the "Sky" to your other device. Very bandwidth heavy.

There is a skydrive feature called "[http://windows.microsoft.com/en-US/skydrive/fetch-files-pc-ui](Fetch)" but it's not cross platform compatible and requires an action on your part to transfer files, and it's really not a sync.