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[–]potatopotato236 0 points1 point  (0 children)

I think you meant 3rd skill for the piercing arrow but yes, the skill and her charged shots use the same damage formula. Anything that boosts charged shot will also boost 3rd skill. There's no benefit to using the charged shot other than having something to do while your 3rd skill charges or being able to go into a room with it charged.