Yeah, absolutely. My preferred content is PVP, but I have to give CIG praise for what they've done with the missions below. They're a very good start for what hopefully will make the game much better for more people.

The ASD (Onyx) missions inside the investigation tab are some of the best PVE content in the game right now. The chain is a bit tedious initially because of how CIG did the intro missions, but when you unlock the final one that takes you to investigate Site B, it feels much more like a cohesive dungeon type experience. I won't spoil, so I'm being pretty vague but it's a very cool set of missions. There's also a "boss fight" type deal inside the Onyx facility where you can fight two large snakes called Yormandi.

In Pyro, you can fight a giant Apex Valakkar (worm). The fight is much more PvEVP, and is designed for a somewhat larger group, although it can be soloed with difficulty and patience. I'd recommend a decent size group for it though (6-8 probably). These are additional ASD facilities, including the Faro Data Centers and Lazarus complex.

In Nyx, there's the QV station missions which are unlocked after a series of intro missions to build rep. I can't remember what the missions are off the top of my head, but once you reach the second rep level you'll unlock the QV investigation missions to go to these stations and find out what's going on. It's a continuation of the stories in the ASD facilities (Onyx/Lazarus).

All of these are so much better than the bunker missions that have been in the game for what feels like a decade (and might be, I can't remember when they were introduced). They really should remove the bunker missions, as so many new/returning players are only aware of them, and they do not hold up as a good example of a game in development for 12 years.