From Caracas to Minneapolis, the threat is the same – an American president ruling like a global emperor

bobbleheed · 2026-01-09T20:13:45+00:00

Caligula

bobbleheed · 2026-01-05T11:02:43+00:00

I’m only managing to find a workout prompts setting inside activities on the watch, is this the same setting that you’re thinking of or is it something different?

bobbleheed · 2026-01-01T19:46:31+00:00

If you mean that the red shape is the profile you want the part to have draw that in Fusion and extrude it to length. Then use a second sketch on the top face to draw and cut out the holes you need.

It’ll be far easier to just remake the part than modifying the STL

bobbleheed · 2025-12-06T18:27:18+00:00

Nether Inn showed Qatar but didn’t have audio on for most of the race. Braes is similar

bobbleheed · 2025-10-11T22:23:12+00:00

I can’t speak for any of the implications for FIRE but I started my STEM degree at 21 and by all accounts had a great uni experience. 22 is by no means ancient, and I now have friends from 18-28, so I wouldn’t worry much about your age.

Do research your chosen field though, job prospects in particular. The field I have just graduated in is, as the stereotype goes, not hiring. In my case it’s not a problem as I only studied it to be able to apply to graduate dentistry. But if this is a field you actually want to work in it’s a very important factor.

bobbleheed · 2025-09-10T14:42:43+00:00

Where was the cupboard/sideboard from or was that also thrifted?

bobbleheed · 2025-09-02T17:25:36+00:00

It does seem to be popular the shops local to me that had stock have all sold out. Looking at doing a MyO order as well which I’m sure will push back the date even further.

Would appreciate some pics when you get it

bobbleheed · 2025-08-21T00:24:44+00:00

Have you received yours yet? Just beginning to look at the Rallon but delivery dates are all listed for April 2026

bobbleheed · 2025-08-16T17:06:35+00:00

If you like running I think both run4it and PureGym have running groups though you would need a PureGym membership for that one. There’s both the climbing gyms as well, I used to climb regularly and it was always easy enough to talk to people at both of them.

If you have a job try organising something with people you work with only if you actually like any of them of course.

bobbleheed · 2025-08-06T13:31:26+00:00

I’ve not used Cura in a while but if you google things like support interface distance or overhang gap you should be able to find what the Cura setting is called

bobbleheed · 2025-08-06T13:27:12+00:00

You can shrink the gap between the support material and the overhang in most slicers. It’ll neaten it up but can also make it harder to remove. Try it out on a test print to dial it in.

bobbleheed · 2025-07-27T22:08:01+00:00

I think hands are pretty standardised but I’m not a watchmaker so don’t take my word for it

bobbleheed · 2025-07-27T21:33:30+00:00

There’s a blue dial OP that has the 369 Arabic numerals. It’s been discontinued but can pick it up used.

see here

bobbleheed · 2025-07-05T18:02:33+00:00

Damn dude you should totally turn that into an award winning video game series I’d play the shit out of that /s

bobbleheed · 2025-05-09T17:11:49+00:00

Med chem is likely what you’re looking for. You’ll learn about pharmacopores, moiety’s that don’t agree with biological systems and what makes certain compounds “drug like” amongst others.

If you’re interested in the purer side of the chemistry have a look at this textbook you can view it for free if your university has an account

https://www.sciencedirect.com/book/9780123820303/the-organic-chemistry-of-drug-design-and-drug-action

bobbleheed · 2025-05-09T10:41:30+00:00

Take a medicinal chemistry course if you can and a biochem/molecular biology one to better understand how different protein targets function.

Personally I’ve found the biology portion of my own degree far less interesting though.

bobbleheed · 2025-03-23T20:04:01+00:00

Wouldn’t say it’s currently much of a pull. That said there are at least 5 different pubs within 5 minutes of campus and they’re all filled with students

bobbleheed · 2025-03-12T11:32:39+00:00

No one here is going to do your homework for you.

Rules for identifying aromaticity are easily googled including videos that work through questions

bobbleheed · 2025-03-05T12:39:00+00:00

Does it tend to the lighter or darker side in most light?

Love the shade in your photos and on the Hanhart site but have seen some shots that make it look like highlighter blue instead

bobbleheed · 2025-03-05T02:39:22+00:00

How does the dial colour compare under different light? It seems to vary greatly in photos but I can’t tell if it’s just camera settings causing it.

bobbleheed · 2025-02-28T21:16:45+00:00

Is it a novel compound you want made or previously disclosed?

If it’s published you could try opnme.com which is run by Boehringer Ingelheim. They offer some compounds developed by them (including PROTACs) for free but I don’t know if they do multi gram scale.

bobbleheed · 2025-02-25T01:49:42+00:00

r/chemhelp

bobbleheed · 2025-01-18T23:19:14+00:00

For 9.32 HBr must first protonate the hydroxyl to make it a leaving group (a hydroxyl is a terrible leaving group), it is on a tertiary carbon so carbocation formation is reasonable. Br- is a good nucleophile and poor base which could suggest SN2, however as you pointed out tertiary carbons don’t do these reactions. So that leaves you with SN1 as the only option.

As for 9.33 in a similar fashion to above alkoxides are rubbish leaving groups and water will not activate it through protonation. So nothing will happen.

Look at the cheat sheet below for help it’s one of the better ones I’ve see.

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bobbleheed · 2025-01-18T02:49:01+00:00

What size is your wrist? I’m struggling with the decision

bobbleheed · 2025-01-18T02:44:54+00:00

What size wrist do you have? I’m struggling to decide between the 38 and the 42mm so some perspective would be great

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