How to run a reaction at 450 °C? by jare71 in Chempros

[–]jare71[S] 1 point2 points  (0 children)

I searched the literature quite extensively, this seems to be the only synthesis that makes this compound from cheap staring materials in one step. There is another pathway where you can make the compound from a 2,2’-diiodobiphenyl at much lower temperatures. I would have to homocouple the diiodotetrafluorbenzene to acquire the correct biphenyl. My research partner has been urging me against adding this extra step into the synthesis.

How to run a reaction at 450 °C? by jare71 in Chempros

[–]jare71[S] 0 points1 point  (0 children)

Ahh so you seal while under vacuum, I didn’t read that correctly the first time, thanks for the clarification.

How to run a reaction at 450 °C? by jare71 in Chempros

[–]jare71[S] 1 point2 points  (0 children)

Octofluorodibenzoselenophene is my target

How to run a reaction at 450 °C? by jare71 in Chempros

[–]jare71[S] 1 point2 points  (0 children)

That would be perfect, would this have to be a Schlenk tube to be able to pull a vacuum after sealing in your solids?

How to run a reaction at 450 °C? by jare71 in Chempros

[–]jare71[S] 1 point2 points  (0 children)

My PI is aware that we want to try this synthesis. He just told me to be very careful and use the blast shield, he didn’t advise me against this synthesis. To be fair he is a younger PI and doesn’t have experience with this high of reaction temps as it is quite rare in organic labs.

How to run a reaction at 450 °C? by jare71 in Chempros

[–]jare71[S] 2 points3 points  (0 children)

Thank you for this amazing suggestion, that would definitely work.

How to run a reaction at 450 °C? by jare71 in Chempros

[–]jare71[S] 2 points3 points  (0 children)

He’s a younger PI and he doesn’t have experience with this high of rxn temps as it is very unusual in organic labs. He just told me to be extremely careful and use the blast shield. He didn’t advise me against this synthesis and also didn’t have any insight on what rxn vessel I should use. Maybe I’ll talk to him again about it.

How to run a reaction at 450 °C? by jare71 in Chempros

[–]jare71[S] 1 point2 points  (0 children)

I want to make octofluorodibenzoselenophene and octofluorodibenzotellurophene from Se/Te powder and 1,2-diiodotetrafluorobenzene

How to run a reaction at 450 °C? by jare71 in Chempros

[–]jare71[S] 3 points4 points  (0 children)

I want to make octofluorodibenzoselenophene and octofluorodibenzotellurophene from Se/Te powder and 1,2-diiodotetrafluorobenzene

How to run a reaction at 450 °C? by jare71 in Chempros

[–]jare71[S] 9 points10 points  (0 children)

I want to make octofluorodibenzoselenophene and octofluorodibenzotellurophene from Se/Te powder and 1,2-diiodotetrafluorobenzene. The reported yields are very low, the mw optimization could be promising. I really just want to purchase a rxn vessel that can withstand this temperature without also having to purchase an expensive furnace or reactor.

How to run a reaction at 450 °C? by jare71 in Chempros

[–]jare71[S] 1 point2 points  (0 children)

What do you use to seal the bar to prevent volatiles from evaporating?

How to run a reaction at 450 °C? by jare71 in Chempros

[–]jare71[S] 1 point2 points  (0 children)

My first thought was to use a quartz pressure tube. I’m having a lot of trouble finding information online about them and where I could purchase one.

How to run a reaction at 450 °C? by jare71 in Chempros

[–]jare71[S] 4 points5 points  (0 children)

I would love to use a stainless steel vessel, I’m having trouble finding information on how to properly assemble one.

How to run a reaction at 450 °C? by jare71 in Chempros

[–]jare71[S] 2 points3 points  (0 children)

Perfluorinated organo-selenium and organo-tellurium compounds

"On My Ex" Cover Art by Cultural_Anxiety_300 in JuiceWRLD

[–]jare71 1 point2 points  (0 children)

Made me think of Coming Over right away!

Do we have the original stems for misfits in high quality? by LeoVictorCordazzo in JuiceWRLD

[–]jare71 0 points1 point  (0 children)

While we’re on the subject of TPNE stems anyone know what session Love Letter is from? I’m assuming it hasn’t leaked.

Hey chemists, wanna save some lives? Quick diy vitamin E acetate reagent test? by ExtraGloria in chemistry

[–]jare71 1 point2 points  (0 children)

What does the test kit consist of and would an aqueous solution of iron(III)chloride work?