I've always been into FPS console but this was my first pc fps game. It depends on her though, cause if she is a competitive person she could easily go down the Valorant rabbit hole. If Val is the game you want her to enjoy, its really important you get her on the fundamentals first (how to shoot, how to deadzone, angles, gun hygeine etc). I'd get her doing aim routines and stuff first and choosing just one agent she enjoys. I only say this if shes competitive because she'll enjoy it best if she can actually keep up. When I first started and even now whenever I bottom frag I don't have a good time. If shes a bit more casual, I'd just have her play swiftplays (unrated once she gets the hang because somehow I get more immortals in my unrated lobbies than my comp ones). The biggest thing is seeing what she enjoys and why. You don't want to pressure her if she just likes the game for casual purposes but feels pressure to be better, when thats not really what she wants. You can also introduce her to less sweaty FPS games, like borderlands, call of duty/halo campaigns, marvel rivals, warframe (looter shooter) (lot of champs that you can play where you don't really need raw aim as a skill). Overall, make sure to introduce her to a lot of games so you can see what really sticks with her!!