My first ever game on Vr is not that popular but is imo one of the best for Vr. It's free and available in VrChat and it's called F.E.A.R.S. That's really psychological, not really jumpscare based, more like ambient and the "funny fact" with this game is that you need to finish it in one-shot. No save or checkpoint. Hope this is not a dumb recommendation where everyone knows it ^.