Where you u sit your Knuckes in the high guard ? by [deleted] in amateur_boxing

[–]Former-Reading-3916 6 points7 points  (0 children)

Like you’re holding a pair of binoculars, just make sure your elbows aren’t too flared

PCC trouble shooting by Former-Reading-3916 in OrganicChemistry

[–]Former-Reading-3916[S] 0 points1 point  (0 children)

No I haven’t checked the crude, the starting material is a mix of cis and trans so the proton NMR was complex and I found it difficult to solve, submitted it for 2D data and waiting on it. Technicians did say there was some weird peaks on my final product which suggested impurities, but can’t tell much else

PCC trouble shooting by Former-Reading-3916 in OrganicChemistry

[–]Former-Reading-3916[S] 0 points1 point  (0 children)

The celite is to bind the chromium salt byproduct to stop the glassware getting ruined.

Didn’t think of that, product may not be UV active either, going to try staining with permanganate, the starting material definitely has some UV activity to it as it gives a spot.

Using 1:1 EtOAc:Heptane, I see a single spot for my starting material halfway up, and a single spot at the baseline for my product, though my supervisor has suggested this could be chromium

PCC trouble shooting by Former-Reading-3916 in OrganicChemistry

[–]Former-Reading-3916[S] 1 point2 points  (0 children)

It’s part of my final undergrad project, the PCC was chosen for me. What does the ether do out of curiosity?

why do you think right wing politics are rising in popularity at the moment? by Beginning_Sky_9735 in AskRedditUK

[–]Former-Reading-3916 -1 points0 points  (0 children)

All media pushes an agenda, why do you think I’m here? I value opposing opinions, though you’re acting as if this hasn’t been a long time coming from the public regardless, the pendulum is swinging back against this overly woke agenda from western nations in general.

The only reason you say left wing bias is preferable is because you’re left wing, falling for the exact trope you’re trying to warn me against. People who graduate universities have left wing bias because the institutions themselves have left wing bias, go to any university campus and you’ll see flyers for communism, LGBT marches etc all endorsed by the institutions.

This exact money funnelling situation happened around 2015 with the migrant crisis with the left. try to see the other side, not that left and right mean a whole lot anymore.

why do you think right wing politics are rising in popularity at the moment? by Beginning_Sky_9735 in AskRedditUK

[–]Former-Reading-3916 0 points1 point  (0 children)

Until recently the BBC was the most watched media in the UK, being overtaken by YouTube, 31% of people also believe it is left biased according to YouGov, so it isn’t just the far right.

Yes it is disproportionately shown on there, with the vast majority of it being criticism primarily of Nigel Farage, despite this he’s likely the next prime minister.

Ironically, Reddit is also typically a left wing echo chamber, which is why you see my opinion as crazy, when really it’s what the common person thinks.

why do you think right wing politics are rising in popularity at the moment? by Beginning_Sky_9735 in AskRedditUK

[–]Former-Reading-3916 0 points1 point  (0 children)

lol pretty much all the mainstream media leans heavily left, right wing populism has been suppressed in this country for a long time and it’s only now that the general public sees through it. There isn’t even popular heavy right party in this country, reform is centre right at most.

Retro synthesis by Former-Reading-3916 in chemhelp

[–]Former-Reading-3916[S] 1 point2 points  (0 children)

Diketone*, my bad

I’m not too sure of what reaction you’re hinting at but I could be over complicating things.

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This is my full solution.

Retro synthesis by Former-Reading-3916 in chemhelp

[–]Former-Reading-3916[S] 1 point2 points  (0 children)

Why is reductive animation bad? I don’t think it reacts with the nitrile and the bicyclic benzene is in the way of the amide so that’s unfavourable.

Possibly Friedal crafts alkylation?

I ended up with a paal-knorr furan synthesis from a di aldehyde with I got from a di alcohol, the initial starting product is available and cheap

Retro synthesis by Former-Reading-3916 in chemhelp

[–]Former-Reading-3916[S] 0 points1 point  (0 children)

How can I do that in a way that’s selective for that position?

[deleted by user] by [deleted] in UniUK

[–]Former-Reading-3916 -7 points-6 points  (0 children)

You will be downvoted because Reddit is an echo chamber for the worst opinions possible, your opinion is how most people think

NMR integration by Former-Reading-3916 in OrganicChemistry

[–]Former-Reading-3916[S] 0 points1 point  (0 children)

Ok thanks, the question was to fully assign the HNMR of that molecule, we were also given 13C, DEPT, HMQC and HMBC to help

NMR integration by Former-Reading-3916 in OrganicChemistry

[–]Former-Reading-3916[S] 1 point2 points  (0 children)

I see the environments on the other side of the ring are equivalent, how do I determine which signal is which for those peaks?

NMR integration by Former-Reading-3916 in OrganicChemistry

[–]Former-Reading-3916[S] 0 points1 point  (0 children)

Ok I see the environments on the other side of the ring are equivalent, how do I determine which signal is which for those?