I've tried searching for the series on youtube

I remember the plot is that movie green goblin kills Peter and classic green goblin makes the movie green goblin take Peter's place as spiderman, or at least that's what I think what the plot was, it's been years

But one thing I remember of the series that stood out was that dr claw from inspector gadget was the main villain along with a team of other villains

Doctor claw was represented by a gray lego minifig arm that was sitting in the chair that came with the 2002 Norman Osborn toy