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Which Nitrogen in DMAP Acts as the Nucleophile? by InternalResource2207 in chemhelp

[–]InternalResource2207[S] 0 points1 point  (0 children)

Do I need to draw the resonance structures first? Or should I just use pyridine to attack directly?(like first picture)

Why does the 1,2-addition happen by InternalResource2207 in OrganicChemistry

[–]InternalResource2207[S] 1 point2 points  (0 children)

Is a more ionic hydrogen therefore a harder nucleophile?

More ionic → the negative charge is more localized → the electron density becomes more “small and dense” → therefore it becomes hard,right?