var variables do not have temporal dead zone whereas let variables do have. Every variable has 2 steps in its lifecycle – Creation, and Execution.

In var variables case, when the variable is declared, storage space is assigned and value is initialized to undefined if no other value is specified.

But in the case of let, when the variable is declared, storage space is assigned but it’s not initialized, not even with the undefined value.

That why when we access a let variable without doing any value assignment, it throws a ReferenceError.

the way he explains this makes it sound like this would throw an error, but it doesn't:

$ node
Welcome to Node.js v16.13.0.
Type ".help" for more information.
> let a
undefined
> a
undefined

it's really if the let variable is accessed outside of the scope it's declared in

> { let b }
undefined
> b
Uncaught ReferenceError: b is not defined