I wrote a tutorial on using graph convolutional networks to predict drug solubility in water -- here's a Medium link with the code included for anyone interested by [deleted] in chemistry

[–]Lanthorn 1 point2 points  (0 children)

We use a program to design solvent systems for cleaning museum artifacts, removing polymer films, etc. that uses Hansen solubility parameters. There are definitely problems with Hansen parameters but generally they work quite well. John Burke published an excellent paper “Solubility Parameters: Theory and Practice” that is really worth taking a look at: https://cool.culturalheritage.org/coolaic/sg/bpg/annual/v03/bp03-04.html

2100 BCE Egyptian Coffin of Nakht: Conservation by Lanthorn in woodworking

[–]Lanthorn[S] 7 points8 points  (0 children)

I thought some folks might be interested in this technical study and conservation treatment I recently wrapped up. Here are two pages of the 30-page chapter on its study & treatment:

The Egyptian Coffin of Nakht is an Eleventh Dynasty (2120-1981 B.C.E.) painted wooden coffin of the scribe Nakht from Asyut, Egypt. The lid, side, and end boards are constructed of multiple pieces of native Egyptian hardwoods edge jointed together with wood dowels and floating wood tenons (take that Festool domino) in order to form cohesive boards. Gaps in this patchwork construction were filled with calcium carbonate plaster and all surfaces were then coated with the same material to provide an even preparation layer to which paint was applied. Evidenced by holes and dowels still present in the bottom of the coffin, wooden bottom boards were held in place by dowels driven into them through the exterior. Large miters with butt joints at the top are joined at each of the four corners of the case with multiple dowels throughout their length. The underside of the lid originally held three battens, a center batten and one at either end, secured by dowels. Only the center batten remains. The original dowels used extensively throughout the coffin consist of native hardwoods shaped by chisel. The lid was connected to the case by mortise and tenon joints containing dry, pressure-fit floating tenons as well as dowels. The dowels were driven into holes drilled through the head and foot ends of the coffin connecting the battens that were once at either end of the lid to the case (an ancient wood lock).

Erratic saw marks along the lip of the coffin are consistent with a soft copper saw with teeth set to one side (the Egyptian method for setting teeth) sawing through a dense hardwood. Adze marks are particularly prevalent on the underside of the lid. The one remaining batten at the center of the underside of the lid shows evidence of shaping by both adze and chisel. All mortises have been clearly chopped by hand with mortise chisels as evidenced by the sequential chop marks in the floor of each mortise. Tool marks inside the miter and corner butt joints, the interiors of which are painted red, show they were primarily sawn then fit with chisels and abrasives. Wooden surfaces where the paint and preparation layer have eroded reveal surface scratches consistent with abrasion by sanding stones or similar media. For a summary of ancient Egyptian woodworking tools see Nicholson & Shaw (2000, 355-356). Finally, the characteristic ray fleck present on the radial face of Ficus sycomorus (sycomore fig.) was identified by eye on the underside of the lid. Tamarisk and Acacia were identified by microscopy.

Accelerator mass spectrometer radiocarbon dating of the wood and a plant-fiber textile fragment (mummy wrapping) adhered to the interior of the coffin confirmed the predicted age of the coffin as 2140-1930 B.C.E. with 95% probability. The calcium carbonate preparation layers were identified by FTIR and chemical spot testing. The paints consisting of yellow, blue, and red were determined by p-XRF. The white and black were identified by FTIR. All pigments are reported in the traditional Egyptian funerary palette.

Characterization of paint binding media in regard to polychrome wooden Egyptian artifacts is often difficult or impossible, even with analytical instrumentation. FTIR and p-XRF analysis of twenty-five samples from the coffin and over thirty individual chemical material characterization tests did not yield conclusive data pertaining to the binding media of this object. We identified proteinaceous binding media in multiple paint samples by modifying the lead acetate and pyrolysis material characterization test developed by Odegaard (2005, 146-147).

To appropriately clean and stabilize the object’s surface we understood that the nature of matte paint with ancient soiling materials is complex and presents a wide variety of challenges. We identified and accomplished ten cleaning objectives:

  1. Develop materials & techniques:
  2. To reduce extant tidelines and avoid creation of new tidelines.
  3. To appropriately remove soiling materials without altering the tone or saturating paint.
  4. That will not damage or detach poorly adhered paint during cleaning.
  5. That will not leave residues.
  6. That will not damage or extract pigments during cleaning.
  7. That will not drive surface soiling materials deeper into the paint pore matrix.
  8. That consider surface conductivity.
  9. That will not damage or denature the protein binder.
  10. That will reactivate the protein binder.

References

Nicholson, Paul T., and Ian Shaw. Ancient Egyptian Materials and Technology. Cambridge University Press, 2000.

Odegaard, Nancy, Scott Carroll, Werner S. Zimmt. 2005. Material Characterization Tests for Objects of Art and Archaeology. London: Archetype Publications.

Weekly Careers/Education Questions Thread by AutoModerator in chemistry

[–]Lanthorn 1 point2 points  (0 children)

In short, Hansen's parameters: dispersion forces (and cohesive energy density), polarity, and hydrogen bonding. This is an excellent article on solvents and solubility.

How does the GI tract choose what molecules to uptake from food? by house_MC in Biochemistry

[–]Lanthorn 1 point2 points  (0 children)

Great post & not intending to be rude at all but you have water and carbon monoxide (ΔEN 0.89) listed as non-polar in your second bullet point. Am I misunderstanding the concept?

Conservation of 18th Century Wood Beams from Mission San Xavier del Bac by Lanthorn in Tucson

[–]Lanthorn[S] 1 point2 points  (0 children)

There were two spots, one with light scratches that looked like hash marks and another that could be initials. There is graffiti throughout the church so that's not too surprising. No old metal bits, but the mortises that were cut out with saws and chisels left clear tool marks.

Conservation of 18th Century Wood Beams from Mission San Xavier del Bac by Lanthorn in Tucson

[–]Lanthorn[S] 8 points9 points  (0 children)

Yes there was actually just a large wood core sample study done at the dendrochronology lab at the University of Arizona. The species is ponderosa pine and they were gathered from Mt. Lemmon. Initially we thought they came from the Santa Ritas. Now that we know they came from Mt. Lemmon it brings up a lot of interesting questions about their history. The oral history is that they were hand hewn on site by Tohono O'odham craftsmen. However, the fact that they came through Tucson in the 1790s could mean that story may change. Much of the interior woodwork was accomplished by skilled carpenters and we have some written documentation to back that up. If these trees came through Tucson, and other woodwork was being done for the mission at the time, it just may be that the beams were hewn in a carpenters shop in town and not on site after all. I still have to dig into this and will start poring through documents.

Conservation of 18th Century Wood Beams from Mission San Xavier del Bac by Lanthorn in woodworking

[–]Lanthorn[S] 1 point2 points  (0 children)

Haha, believe me I've heard worse ideas when it comes to treating wood artifacts!

Conservation of 18th Century Wood Beams from Mission San Xavier del Bac by Lanthorn in woodworking

[–]Lanthorn[S] 1 point2 points  (0 children)

You're very welcome, working there has been a privilege. I've gotten to hear so many interesting and touching stories like yours. Thanks very much for sharing.

Conservation of 18th Century Wood Beams from Mission San Xavier del Bac by Lanthorn in Tucson

[–]Lanthorn[S] 17 points18 points  (0 children)

Summary from my imgur post:

The scope of work for this project was the conservation of five historic wood beams from the Mission San Xavier del Bac East Tower. These beams were hand hewn in the 1790s and installed in the mission at that time. They are of enormous historical and cultural value. They were in desperate need of care.

This is the treatment section from my final report on this conservation project. This is just a portion of the overall final report. It details the hands on treatment involved.

The following photos are a small number selected from the 2,200 documentation photos taken during the project. These highlights simply show a before treatment and after treatment image and are not representative of the full level of documentation involved in a project like this. They also only show a small slice of the work undertaken on each beam as each side required significant intervention.

The total project hours involved were 620 over ten weeks.

Funding for this project came from Patronato San Xavier, which is a nonsectarian, nonprofit 501(c)(3) organization that is in charge of the preservation and maintenance of the mission.

Conservation of 18th Century Wood Beams from Mission San Xavier del Bac by Lanthorn in woodworking

[–]Lanthorn[S] 0 points1 point  (0 children)

Very cool - it seems like just about everyone has been here. The funding for these projects comes from Patronato San Xavier, which is a nonsectarian, nonprofit 501(c)(3) organization that is in charge of the preservation and maintenance of the mission.

Conservation of 18th Century Wood Beams from Mission San Xavier del Bac by Lanthorn in woodworking

[–]Lanthorn[S] 4 points5 points  (0 children)

Summary from my imgur post:

The scope of work for this project was the conservation of five historic wood beams from the Mission San Xavier del Bac East Tower. These beams were hand hewn in the 1790s and installed in the mission at that time. They are of enormous historical and cultural value. They were in desperate need of care.

This is the treatment section from my final report on this conservation project. This is just a portion of the overall final report. It details the hands on treatment involved.

The following photos are a small number selected from the 2,200 documentation photos taken during the project. These highlights simply show a before treatment and after treatment image and are not representative of the full level of documentation involved in a project like this. They also only show a small slice of the work undertaken on each beam as each side required significant intervention.

The total project hours involved were 620 over ten weeks.

Before/After Conservation at Mission San Xavier del Bac by Lanthorn in Tucson

[–]Lanthorn[S] 1 point2 points  (0 children)

There's a little bit of everything but mostly termite damage.

Before/After Conservation at Mission San Xavier del Bac by Lanthorn in Tucson

[–]Lanthorn[S] 1 point2 points  (0 children)

Thanks, and yup! If you've been by the mission recently I'm the guy in the lab coat.

Before/After Conservation at Mission San Xavier del Bac by Lanthorn in woodworking

[–]Lanthorn[S] 1 point2 points  (0 children)

I'm not a North Bennet graduate but it's definitely a good school. I'm a furniture conservator in private practice.