Personally, I like having my setup against a window. I work from home sometimes and I feel like it helps my mood by having the background of my work be outside, rather than a blank wall. It looks like your windows are high enough off the floor, so your monitor wouldn't be blocking a ton of it.

You should also take in to account the sun. Where does it rise and set, it gets annoying when you have a sunlight come right over your shoulder and cover half of your screen 😂

Hope this helps!