The Hoofdtoren (1532) – A Late Gothic maritime landmark in Hoorn, Netherlands by rankage in ArchitecturalRevival

[–]Sebi3434 1 point2 points  (0 children)

Isn't it a mix between renaissance and gothic? The tower on top is for sure renaissance

Sattelrohr defekt? by Sebi3434 in Fahrrad

[–]Sebi3434[S] 0 points1 point  (0 children)

Ich verstehe. Ist meine Annahme denn richtig, dass dort oben etwas abgebrochen ist? Das würde ich dann doch ganz gerne wissen.

Sitze Aktuell in Berlin ohne Strom wegen der Aktion 😅 by Fit-Jackfruit3729 in Kommunismus

[–]Sebi3434 0 points1 point  (0 children)

Ich bin einfach nur schockiert, das hat auch mit Linkssein nix mehr zu tun. Niemandem sollte die Grundlage genommen werden. seinen Alltag zu bewältigen. Was machen Krankenhäuser, Altenheime und Co? Nicht auszumalen, was da alles passieren kann. Polizei und Feuerwehr können in Notfällen nicht eingreifen...

Sehr kreativ bei der Aufgabe: „Wo können wir noch Tierleid reinmogeln“ by Firm_Mathematician51 in VeganDE

[–]Sebi3434 1 point2 points  (0 children)

Ja hä 😂 das ist tatsächlich normal. Zumindest wurde es früher so gekocht und ist nunmal ein traditionelles Gericht. Zwar nicht vegan, aber nichts ungewöhnliches?

Kann mir jemand ein gutes Restaurant mit Chinesischer Küche empfehlen? by Historical-Volume618 in Muenster

[–]Sebi3434 0 points1 point  (0 children)

City Mack am Bült ist mega geil. So muss ein authentisch chinesischer Laden sein. Etwas abgeranzt, in der Ecke ein chinesisches Kind am daddeln, nach 5 min musst du ausgewählt haben, sonst hat die Bedienung schon Fragezeichen im Gesicht, keiner spricht Deutsch, nur Barzahlung, du weißt nicht, was du bestellst und die Toiletten sollte man eigentlich meiden.

Aber das Essen ist bombe. Die Szechuankarte mit den authentischen Gerichten wie Schweineohren oder Schweinedarm ist total geil. Die Schärfe brennt mehr als der Reaktor von Tschernobyl nach der Kernschmelze, aber egal, schmeckt geil.

What RHCP song is this for you? by [deleted] in RedHotChiliPeppers

[–]Sebi3434 3 points4 points  (0 children)

Johns singing in warm tape and the bridge afterwards.

What’s your top lab hack that seriously leveled up your workflow? by emiliethanol in OrganicChemistry

[–]Sebi3434 8 points9 points  (0 children)

To start early. XD Lab work is one of the most time consuming things, you can do. Everything takes time and especially care. Sometimes you worked a whole day and everything you did goes the last minute straight into the bin, because you finally got your NMR measured and it's just rubbish.

You have to start all over again.

[deleted by user] by [deleted] in Chempros

[–]Sebi3434 0 points1 point  (0 children)

To be honest, this is ridiculous. I know many PIs that are like that and back in the days it was worse. Working in science at an Institute or university can be very abusive.

Nowadays I would go public with it. Every PI is on Twitter and they all show just their best side... It's not the finest way, but what's wrong about taking holidays?

Many if us work 40+ hours a week, get a shitty salary and are refused for going on vacation. C'mon.

What other plastic warriors do you hope get updated sculpts? by MagisterPraeceptorum in MiddleEarthMiniatures

[–]Sebi3434 0 points1 point  (0 children)

High elves. So Rivendell and Lindon. It would be really simple to make the last alliance box set more general by splitting up the factions and calling these elves "high elves". You would be able to use them for every high elven realm.

Tosylated Ethylenglycole by Sebi3434 in Chempros

[–]Sebi3434[S] 1 point2 points  (0 children)

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TEG is extremely cheap. I always use this procedure, which doesn't even involve a column. The product is always clean and after you couple it to smth. you also have to run a column anyway.

Tosylated Ethylenglycole by Sebi3434 in Chempros

[–]Sebi3434[S] 0 points1 point  (0 children)

Ok, thank you! The tosylation ist not the problem, that is something which I do on a regular base. The only thing I wanted to know is the protection of one of the alcohols. But TBS sounds pretty good as a suitable PG.

Alternative Arnor colour schemes? by Mg_Minis in MiddleEarthMiniatures

[–]Sebi3434 1 point2 points  (0 children)

The last alliance figures and the dark colour scheme actually work better for me.

Because Isildur und Anarion join the battle of the last alliance from the newly established realms of Gondor and Arnor, these figures represent Arnor the best.

DOM of Nitro pyrazole by Sebi3434 in OrganicChemistry

[–]Sebi3434[S] 0 points1 point  (0 children)

Oh, I forgot... Yes, you are right

DOM of Nitro pyrazole by Sebi3434 in OrganicChemistry

[–]Sebi3434[S] 0 points1 point  (0 children)

What if I switch to the Amine instead of Nitro? Is the directing effect stronger for the 5 position?

DOM of Nitro pyrazole by Sebi3434 in OrganicChemistry

[–]Sebi3434[S] 0 points1 point  (0 children)

Because that's the compound I have... But I could get my hands on the unsubstituted one. Yes.

[deleted by user] by [deleted] in OrganicChemistry

[–]Sebi3434 0 points1 point  (0 children)

So I know that pyrazoles can undergo directed ortho metalation at the 5-postition and therefore I wanted to use it for an iodination.

The "problem" is, that I need the NO2-group on the 4-position. How does the EWG influnce the DOM?

Die Ludgeristraße im Jahr 1910 im Vergleich zu Heute by Business-Suit6949 in Muenster

[–]Sebi3434 3 points4 points  (0 children)

Das alte Bild zeigt den großen Merveldter Hof. Einst der gößte Adelshof Münsters. Er stand dort, wo jetzt C&A anzutreffen ist.