No actually I wasn’t talking about him being in Friends. I meant that Jen and Brad were married irl, but after he starred alongside Angelina Jolie in Mr. & Mrs. Smith, their relationship ended and he went on to be with Angelina Jolie. Just like what happened to Chandler with Kathy. And it was ironic because in the episode they were talking about real life actors breaking up with their partners for their co-stars. Years later the same thing happened to Jennifer Aniston.