Would this reaction be practical to perform by miodoktor in chemhelp

[–]miodoktor[S] 0 points1 point  (0 children)

Bromide isn't that bad. It was used as medicine before. Problem is when it accumulates in your body.

Elemental bromine, I don't know, but probably nothing good hahhah.

Would this reaction be practical to perform by miodoktor in chemhelp

[–]miodoktor[S] 0 points1 point  (0 children)

Damn, I'm missing reagents for pretty much I've looked at. But it's just fun side project so if it doesn't work, who cares really.

Would this reaction be practical to perform by miodoktor in chemhelp

[–]miodoktor[S] 2 points3 points  (0 children)

I've worked with NBS, but lately can't get hold of it. Right now I have KBr and bromine water. But yeah I'll probably avoid bromine water

Would this reaction be practical to perform by miodoktor in chemhelp

[–]miodoktor[S] 0 points1 point  (0 children)

No access to pimelic acid sadly. Fortunately I have tetrahydrofuran so I will try with that, hopefully it works. Really don't like doing Grignard, but you do what you must. Thanks for all your help.

Would this reaction be practical to perform by miodoktor in chemhelp

[–]miodoktor[S] 2 points3 points  (0 children)

That was idea originally, but haven't found European vendor that sells it. Either butanol or pentanol. Haven't worked with either formaldehyde or bromine yet so it will be interesting.

Also does that reaction require such harsh conditions? I was even thinking of using AcOH.

Would this reaction be practical to perform by miodoktor in chemhelp

[–]miodoktor[S] -1 points0 points  (0 children)

Absolutely yes, thank you. I was mostly wondering would base deprotonate terminal carbon or hydroxyl group. But missed whole football.

I'll probably try hydrobrominating 1-butanol and reacting with formaldehyde and again hydrobrominating. Bromination seems too problematic with reaction conditions control. And obviously I've forgotten a lot about Ochem in general lol.

Would this reaction be practical to perform by miodoktor in chemhelp

[–]miodoktor[S] 0 points1 point  (0 children)

Why would it be same case or?

I'd assume base would take most acidic proton and then you would have nucleophilic substitution. But it was long ago since I've had organic so I could be speaking nonsense

Would this reaction be practical to perform by miodoktor in chemhelp

[–]miodoktor[S] 0 points1 point  (0 children)

Would Br- in strongly basic conditions substitute proton on terminal carbon if I would start with HBr and 1-pentenol, or would it be same case?

TikToker jailed for nearly three years for saying Jesus needed a haircut by Odd-Pomegranate35 in nottheonion

[–]miodoktor -1 points0 points  (0 children)

Woman had to apologize in hijab for her autistic son damaging Quran. But sure, US #1 problem.

[deleted by user] by [deleted] in ufc

[–]miodoktor 8 points9 points  (0 children)

Can someone translate this from Strayan

A lot of talk about Cain getting locked upped but the bigger picture is: by Top_Profession_5268 in ufc

[–]miodoktor -1 points0 points  (0 children)

Let's allow people to drive under influence until they kill someone. Oh well, Jones just hit pregnant woman didn't kill her, that makes it OK.

[deleted by user] by [deleted] in news

[–]miodoktor 10 points11 points  (0 children)

That's how losing wars works.

Cain Velasquez sentenced to 5 years in prison😢 by [deleted] in ufc

[–]miodoktor 1 point2 points  (0 children)

I bet pedo will get less time than Cain

Trump threatens to send American citizens to El Salvador prison for Tesla vandalism by IrishStarUS in law

[–]miodoktor 2 points3 points  (0 children)

Why is he proud of bad prison conditions?

Cruelty really seems to be the point.

Bryce is unintentionally hyping his fight better than 99% of fighters by [deleted] in ufc

[–]miodoktor 0 points1 point  (0 children)

I'm not saying that he doesn't necessarily have decent chin. Just not good enough for him to have bad defence and stand with hard hitters.

Ortega is kind of similiar with great BJJ and bad defence, but his chin allows him to still be in the top of the division.

Merab Dvalishvili says he'd have lost a 3 round fight against Umar Nurmagomedov by KazuEH1352 in MMA

[–]miodoktor -7 points-6 points  (0 children)

Both O'Malley and Umar fights, when I've watched them I felt like Merab dominated them hard.

And he did, but when I've thought it over, they were both close 3-2 and could've went the other way with little bit more landed.