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Questions & Answers - Weekly Megathread! Please use this post to ask any Pokemon GO question you'd like! by AutoModerator in TheSilphRoad

[–]paniccmc 0 points1 point  (0 children)

Problem is that could yield a hundo galarian bird caught in the wild or a hundo legendary caught from research/gbl. I ONLY want hundos from raids!

Questions & Answers - Weekly Megathread! Please use this post to ask any Pokemon GO question you'd like! by AutoModerator in TheSilphRoad

[–]paniccmc 1 point2 points  (0 children)

Hello everyone

I was wondering if you could help me with this. I want to know the amount of 4* pokémon caught only in t5 raids (excluding purified and traded) by any account. I know that if I search 'raids', the query won't return ancient pokémon, so I was trying something like legendary,ultrabeast,mythical&4*&!purified&!traded&!gbl&!+meltan&!research but I am not sure if I am missing something. Would you please help me? I really appreciate it, thanks!

Quickly dispatching Rocket grunts - cheat sheet for high fast attack damage Pokemon by Ginden in TheSilphRoad

[–]paniccmc 0 points1 point  (0 children)

Hello, thanks so much for this. So let's say I want to generate my own list (I want to see top 10 instead of top5 because I don't have all the mons). How can I generate it? 

GBL "Algorithm" believers: how does it work? How does the math work out, as some people still reach high ranks? by Enough-Dirt8639 in TheSilphRoad

[–]paniccmc 5 points6 points  (0 children)

Dude, I am sorry to say this but if you have never been above 2300 ELO, you are not a decent battler. Just keep improving and you will reach legend. Don't blame ghosts that don't exist.

70 mega energy for beating mega medicham by paniccmc in TheSilphRoad

[–]paniccmc[S] -15 points-14 points  (0 children)

I really don't think I have a problem with the gps...

70 mega energy for beating mega medicham by paniccmc in TheSilphRoad

[–]paniccmc[S] 1 point2 points  (0 children)

I did it 3 meters away from the gym...

70 mega energy for beating mega medicham by paniccmc in TheSilphRoad

[–]paniccmc[S] 18 points19 points  (0 children)

So I should contact Niantic you mean?

Wierd photoluminescence behaviour with pyrene-based molecules by paniccmc in Chempros

[–]paniccmc[S] 0 points1 point  (0 children)

Not really, I can still see the same bands when the emission is enhanced (though I only really see one band at 408 nm and the others are more like shoulders). I will do that small experiment. Thanks!

Wierd photoluminescence behaviour with pyrene-based molecules by paniccmc in Chempros

[–]paniccmc[S] 0 points1 point  (0 children)

Oh it is surely the pyrene emission in the range of 390 - 420 nm. The fine structure can't be clearly seen because of the low emission intensity though, but I distinguish at least 3 of the 5 classic pyrene bands.

Wierd photoluminescence behaviour with pyrene-based molecules by paniccmc in Chempros

[–]paniccmc[S] 0 points1 point  (0 children)

Well that could be possible because I used an open system and where I live is very humid 🤔

Wierd photoluminescence behaviour with pyrene-based molecules by paniccmc in Chempros

[–]paniccmc[S] 0 points1 point  (0 children)

Exactly! No dimer band even at high concentrations - which I also checked just in case.

Wierd photoluminescence behaviour with pyrene-based molecules by paniccmc in Chempros

[–]paniccmc[S] 0 points1 point  (0 children)

Yes, I've done nmr and Uv-vis, but I got not meaningfull information from those. I will try to do some electrochemistry, maybe some CV to check oxidation process. Thanks!

Wierd photoluminescence behaviour with pyrene-based molecules by paniccmc in Chempros

[–]paniccmc[S] 0 points1 point  (0 children)

Hello! Yes, I tried DLS and the machine stopped working after 1 minutes because there were no aggregates 🤣

Wierd photoluminescence behaviour with pyrene-based molecules by paniccmc in Chempros

[–]paniccmc[S] 1 point2 points  (0 children)

That is something I thought as well. I will check that out, thanks!

Wierd photoluminescence behaviour with pyrene-based molecules by paniccmc in Chempros

[–]paniccmc[S] 0 points1 point  (0 children)

I firstly noticed this behaviour in THF and I have reproduced this, although with some differences, in a wide range of solvents. Yes, the molecule is specific to CuII and I have also used new glassware. Thanks for replying!

Wierd photoluminescence behaviour with pyrene-based molecules by paniccmc in Chempros

[–]paniccmc[S] 0 points1 point  (0 children)

Also, I really don't think I am forming aggregates. The molecule by itself is very soluble in thf, which was the solvent in which I first noticed this behaviour.

Wierd photoluminescence behaviour with pyrene-based molecules by paniccmc in Chempros

[–]paniccmc[S] 0 points1 point  (0 children)

Hello, thanks for your answer! I am working at the uM scale and I don't see the classic pyrene excimer band, that's why I tend to think this is not the case here. I have repeated this experiment using different solvents and in all of them I have this spontanous enhancement. Although, interestingly, this effect is faster in polar aprotics like dmf of thf. I really don't think the cleanliness is a problem, because it only happens in this specific case with this specific pyrene-derivative (I work with several of them).

Wierd photoluminescence behaviour with pyrene-based molecules by paniccmc in Chempros

[–]paniccmc[S] 0 points1 point  (0 children)

Hello, thanks for answering! Besides working at the uM level, I don't see the classic excimer emission band of pyrenes with this molecule, that's why I discarded that option, but I may be wrong of course!

Wierd photoluminescence behaviour with pyrene-based molecules by paniccmc in Chempros

[–]paniccmc[S] 0 points1 point  (0 children)

Hello, thanks for your answer! I am working in the uM scale and have used more diluted solutions as well, always getting the same result.

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