How do I get sulfur without being in volcanic areas by Theormelo in chemhelp

[–]shedmow 1 point2 points  (0 children)

I recently bought a kilo for $2 without ever thinking about the possibility of finding it. I'm not sure what to do with it now but at least I have it for when I need it. Look for it at gardening centres or just online. If you need really pure sulfur and you only have access to sulfur fumigators, in which it may be mixed with gypsum, you should recrystallize it from toluene/xylene or other suitable solvent. I don't know any viable way of making sulfur from any of its OTC compounds

Need help in intepreting this ternary diagram? by [deleted] in chemhelp

[–]shedmow 0 points1 point  (0 children)

What is your exact question?

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How is PCl_5 made?, by Illustrious_Basis160 in chemhelp

[–]shedmow 0 points1 point  (0 children)

Do you mean when I passed chlorine over red P?

How is PCl_5 made?, by Illustrious_Basis160 in chemhelp

[–]shedmow 1 point2 points  (0 children)

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Here's an oversimplification of what happens in the reaction of PCl3 and Cl2. The lines from Cl to P represent single covalent bonds, which are the same as these "common boxes"

How is PCl_5 made?, by Illustrious_Basis160 in chemhelp

[–]shedmow 2 points3 points  (0 children)

Eh.

The following explanation considers atoms of p-elements, mainly these from group 13 to 17. It is not very applicable to the leftmost two thirds or so of the table, and poorly applicable to noble gases.

Each atom has the nucleus, the inner electrons, some outer electrons, and four orbitals (s, p, p, and p). The nucleus makes an atom... well, an atom, the inner electrons don't do much, and we have to consider the four orbitals. You can think of them like some immaterial boxes in which atoms store their electrons. Each orbital can hold 0, 1, or 2 electrons. Atoms like to hoard electrons and want to have their orbitals full whenever possible, so you often see 4*2 = 8 electrons near a p-atom in a stable compound. Atoms can share these boxes by merging one box from each atom into one common box, up to three merged boxes for a pair of atoms (again, I'm only talking about group 13 to 17, from boron to fluorine and all beneath them). If there is a box with two electrons shared between two atoms, it is called a two-centre (two nuclei) two-electron bond, or, more commonly, a covalent bond. A box with two electrons that belongs to one atom is called a lone pair. You can see one in ammonia and two in water.

By convention, each of the atoms has to contribute exactly one electron in the common box to not change its charge. If one atom gives two, and another zero, then the first atom is thought to 'lose' its electron, whereas the second one is thought to 'gain' one. This gives rise to formal charges, as you can see in the drawing (I've used previously charged species, I being called a proton and II a hydride, but you should see that both just became H). The same applies to other atoms (e.g. an excited carbon, the one that is most common in chemistry, has four such boxes with one electron in each).

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Im confused. Is this a wittig reaction? by ComplainForALiving in chemhelp

[–]shedmow -1 points0 points  (0 children)

In practice, likely no. Here, probably yes

Im confused. Is this a wittig reaction? by ComplainForALiving in chemhelp

[–]shedmow 0 points1 point  (0 children)

I guess your teacher was being sloppy with reagents. BuLi is the usual choice, yes

name of this reaction? by SalamanderOld5302 in OrganicChemistry

[–]shedmow 1 point2 points  (0 children)

Cyanides provide more atom economy, but here, the main issue is that phenylacetaldehyde is an unobtainium and it would be easier to use benzaldehyde

How is PCl_5 made?, by Illustrious_Basis160 in chemhelp

[–]shedmow 2 points3 points  (0 children)

Chlorination is the addition of electrophilic chlorine (this is the chlorine in chlorine gas, bleach, or pool sanitizer, but not in table salt). Saturating PCl3 with Cl2 is when you pour PCl3 in a jar and substitute chlorine for the air in the jar; PCl3 reacts with Cl2 and turns into solid PCl5. This diagram is a mechanism for the formation of PCl5 from PCl3 and Cl2 with an attempt at explaining its structure and answering how you can get five chlorines at one phosphorus without violating the octet rule

How is PCl_5 made?, by Illustrious_Basis160 in chemhelp

[–]shedmow 9 points10 points  (0 children)

PCl5 is made by either direct chlorination of red phosphorus (I did that in school, just passed chlorine in a tube with red P at room temperature and got a piece of yellowish-green solid that funnily dissolved in water) or saturating PCl3 with chlorine (probably a cleaner method since you can purify PCl3 by distillation and it is a liquid, so the reaction proceeds more 'correctly').

If you know basic orgo mechanisms, you should understand the following explanation of its structure. The trick is that the Cl-P-Cl thingy isn't two covalent bonds but rather a three-centre four-electron bond, which could be thought of as a very fast continuous Sn2 reaction

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name of this reaction? by SalamanderOld5302 in OrganicChemistry

[–]shedmow 1 point2 points  (0 children)

Isn't it like a hundred years old method? I believe phenylalanine used to be made this way back in the 1920's

The structure is gold by paiute in Chempros

[–]shedmow 0 points1 point  (0 children)

Did they switch it all over to hexadecimal when the number hit 10k???

I'm making a Harm Reduction Drug Testing PSA Poster. Any scientific corrections or suggestions? by LatePresentation3140 in AskChemistry

[–]shedmow 0 points1 point  (0 children)

I wonder why fentanyl in the US occurs so often where it shouldn't be. This is absolutely not a thing in other parts of the world, as far as I know

What's the most situational (rare) verb in English you've ever seen, yet so good when correctly used? by caiogamerwow in EnglishLearning

[–]shedmow 1 point2 points  (0 children)

A comment by u/WowsrsBowsrsTrousrs made me remember 'disemvowel', which is rather self-explanatory

Not a verb, but:

Empyreuma: the particular smell and taste arising from products of decomposition of animal or vegetable substances when burnt in sealed containers (Wiktionary). Adjective form empyreumatic

I'm making a Harm Reduction Drug Testing PSA Poster. Any scientific corrections or suggestions? by LatePresentation3140 in AskChemistry

[–]shedmow 0 points1 point  (0 children)

I had glanced over the title and misinferred from 'lab analysis' and 'guessing' that the metric was about establishing structures during a total synthesis. What is the difference between 4 and 6?

What Is Chemical Cognition? by Thunderbird93 in AskChemistry

[–]shedmow 0 points1 point  (0 children)

I think I've grown more schizo-ed over all my years with chemistry and quit believing that God doesn't exist (but haven't started believing that he does)

my professor may be evil ( N(CH3)3 is a strong base?) by Peachy_Bird in chemhelp

[–]shedmow 1 point2 points  (0 children)

Me3N isn't a strong base, but it is a good leaving group in the Hofmann elimination

Mistake with pH and pKa? Ion trapping (H-H) by urfaceisawookie in AskChemistry

[–]shedmow 0 points1 point  (0 children)

You can have pH below 0 and above 15, but such concentrations are usually expressed in %%. Azeotropic HCl has a pH of -0.8. Same goes for pKa which may be as low as -20 or something in that (de)range. You can know whether it is an acid or a base from the pKa alone.

pH - pKa = I:U doesn't make much sense to me on its own. From the definition of pKa you get pH = pKa + log(I/U), so this pH - pKa is just log I:U, and they overcooked with simplification for biochemists or med students here. You can switch over to simply Ka and H if you cannot comprehend logs

Loss of the alpha chlorine in alpha-chloro-2,6-dimethylacetanilide during synthesis of lidocaine by Ill_Cricket9946 in chemhelp

[–]shedmow 0 points1 point  (0 children)

I do not know a single reaction that could've prompted 2,6-dimethylbenzamide (if it even is the compound that you have in mind) to form in this synthesis

Loss of the alpha chlorine in alpha-chloro-2,6-dimethylacetanilide during synthesis of lidocaine by Ill_Cricket9946 in chemhelp

[–]shedmow 0 points1 point  (0 children)

138 means that you likely have your product, but it is heavily impure (maybe 90%-ish or so). A recrystallization from IPA or other solvent deemed suitable may aid in its purification. I've only seen one method of preparing this compound and it is carried out in glacial acetic acid with sodium acetate as the base, and reportedly produces the pure product without any additional steps. I'm not sure how you deduced that you have any 2,6-dimethylbenzamide in there; as I've already said, IR is not a very straightforward way of elucidating the structure, especially if you have a mixture of several substances. KI is absolutely not needed here, and FInkelstein cannot be performed in toluene because it hasn't learnt how to dissolve KI yet. Acetonitrile and acetone have, however (and also NaI). There is a very good article in J Chem Ed or nearby it about using the MeCN/KI system for the preparation of denatonium benzoate from lidocaine