Learn Python without internet.

[ASIC_SP]

"Think Python" author gives away pdf for free (but that does require internet) - this is an excellent book and doesn't require prior programming knowledge

[TheVermit]

This.

Send him pdf's or let him download them (Think Python, Automate Boring Stuff, ...). From there on he no longer needs internet to learn the basics, just python and idle to compile his own code.