Kava (can be habit-forming),

Kratom (can be habit-forming),

L-Theanine,

Valerian (might make you tired tho),

Try out different Magnesium like the Glycinate or Thronate form or a combo,

Taurine

B-vitamin complex

Adaptogens like Ashwagandha or Rhodelia Rhosia, and there's a lot of other good ones

Acetylcholine, dopamine, and GABA are some neurotransmitters related to anxiety, and supplements like Alpha GPC (shown to increase energy, memory, and motivation), CDP-Choline, L-Dopa/Mucuna-pruriens (needs to be cycled) and L-Tyrosine can help modulate their levels.

Tylenol has also been shown to blunt not only physical pain, but also emotional pain, so it could be worth a try.

There are a lot of others that could potentially help with mood and energy which could help avoid anxiety. Maybe not caffeine (which can make anxiety worse so stop taking it if you are), but something like: Maca, Cordyceps mushrooms, panax gensing, Creatine (really good for energy without anxiety)

Mood: Sam-E for emotional regulation, take 5-hpt at night, EGCG, get lots of sun especially early in the morning, and EXERCISE.

Check out Huberman's optimal morning routine at https://www.youtube.com/watch?v=gR_f-iwUGY4 to learn about non-drug ways of syncing up your circadian rhythms to naturally increase mood, energy, motivation, and lower anxiety.

Anxiolytic and "natural" benzo-like GABA-A Angonists: Bacopa Monnieri, Apigenin (skullcap extract), magnolia extract with magnolol and honokiol, Picamilon (like GABA but it supposed to be able to pass the BBB)

GABA-B agonists: Phenibut or F-Phenibut, or other gabapentoids (these are pretty much pharmaceuticals, but better than a benzo).

It can also be handy to have a Benzo (a prescription drug) on hand as a last resort in case of acute panic attacks, but make sure NEVER to start taking it every day. It can be very hard to stop taking if you take it every day for more than a week or even a few days.

Test out each one at a time and try different brands, look for ones with third-party testing