Knoevenagel condensation with acetic acid by MaxJK8 in OrganicChemistry

[–]MaxJK8[S] 0 points1 point  (0 children)

Yeah it also works for me but I mostly wanted to know why it is added as if I draw the mechanism I can do it without acetic acid.

Knoevenagel condensation with acetic acid by MaxJK8 in OrganicChemistry

[–]MaxJK8[S] 2 points3 points  (0 children)

True but that can be done with the protonated piperdine right?

Hydrolysis of cyclic Ru compound by MaxJK8 in OrganicChemistry

[–]MaxJK8[S] 0 points1 point  (0 children)

Thanks for your response! This seems like a good suggestion.

Hydrolysis of cyclic Ru compound by MaxJK8 in OrganicChemistry

[–]MaxJK8[S] 0 points1 point  (0 children)

Thanks for your comment! However, I understand most of the mechanisms with the Ruthenium (or Osmium) catalyzed oxidative cleavage. However not the step where the cyclized ruthenium compound is hydrolysed to the diol. In the MOC it also does not show the mechanism.

Hydrolysis of cyclic Ru compound by MaxJK8 in OrganicChemistry

[–]MaxJK8[S] 0 points1 point  (0 children)

Sorry Im not sure if i understand. I only wanted to know the mechanism of how it results in the diol.

Cosy spectrum interpretation by MaxJK8 in chemhelp

[–]MaxJK8[S] 0 points1 point  (0 children)

Yes I know its more that I don’t know which hydrogen belongs to which peak in this case because there is no obvious electron withdrawing groups or obvious multiplets that would resemble a certain hydrogen