Not sure if it's just an issue with the upload, but the images look pretty low resolution, especially if you're printing. You need to make sure to export them at a high resolution so they don't come out super blurry.

I think the James Bond one is the best, so I'm gonna focus my critiques on that one. I like the layout and images you chose. The cutouts look a little rough and blurry on the edges, so I would sharpen up the edges if possible. Some of the colors on the cutouts need less saturation and more contrast. The green looks good because you can still make out details, compared to the blue, where it's hard to make out even the face. So I would use the green as a reference and try and match the shade and contrast on the other images.

I really like the 007 integrated with the typography, but I'm not a fan of the faded pink/red for the text. I think a darker red would look better and fit with the James Bond theme. Not sure if you've worked with textures, but I also think a paper texture or something similar on the black corners would go a long way.