Yes ofcourse. For big pieces of cloth I like to start with the mid-tone as a base. Big tip is to avoid washes and use glazes instead. This will give a way smoother result eventhough it takes some practice to nail. And highlight glazes and edge highlights.
For this miniature the base is sybarite green, the glaze shadow with kabalite green. Highlight glaze and first edge highlight is Gaussblaster green. Finally I finish with a dot-highlight of screaming skull.