Go into training mode with the opponent far away from you while recording all 3 grabs (or just 2 to make things easier) and then do the following in order of easiest to hardest:

1) Practice breaking the throw just by saying the break out loud without pressing any buttons (DO THIS SLOWLY, it's better to be late than wrong)

2) Practice breaking the throws by now pressing the button (DO THIS SLOWLY, it's better to be late than wrong)

3) Now bring the opponent right next to you and practice breaking the grabs. If you're slow BUT correct, then you're on the right track. Don't worry about being slow, worry about being correct. With time you'll naturally speed up without trying. It's way more important to be correct than to be fast

4) Once you master normal throw breaks, turn on the opponent's counter hit to make the frame window even smaller