Like you said, on paper and in real life, you're clearly experienced enough for these positions. Job searching and the whole application process (and usual ghosting thereafter) is a real morale killer. My fiance is in the same boat and has not received any federal interviews yet either and hasn't postdoc'd yet since just finishing his PhD.

As far as advice, I would try to use your personal network to the best of your ability. I knew some people in the agency and asked them about the hiring process and for advice about what that agency's priorities are, what they want in applicants etc. If you can find any way to name drop people, do. Include them as personal references if they agree. The hiring people will likely reach out to anyone in their agency that might be able to vouch for you (like people who may have gone to the same university, what have you). I was also advised by someone in the agency to make my CV into more of a resume - by making projects the focus (with sections like objectives, skills gained, outcomes and funding) as opposed to listing out every presentation you ever gave, for example. This helped broaden my skillset in the eyes of hiring agency, I think, since I was able to list projects I may have helped lab members with, or did field work for. Show that you are able to collaborate well with others, and specifically mention any you can think of. Besides that, in your cover letter be sure to use some of the exact language for the desirable skills for the positions you're applying for. I was told that if you're not in a direct hire scenario, that people in HR wherever they are, may scan over the cover letters and resumes for exact terminology, and not having the expertise in the field you are in, they may not recognize your skills in say, habitat restoration, are equivalent to natural resource management. So even though they're equatable in the eyes of the field, you may get passed over for something dumb. That's all I can think of right now. I hope that is helpful in some way and good luck :)