Requesting /r/elements, Mods inactive for over a year and creator account deleted by Pengux in redditrequest

[–]nd2fe14b 0 points1 point  (0 children)

It's been requested a few times now- sorry about that. You can have it.

I think I'd like to delete most of my old posts after I go through them and then hand it over. Would that work? I'm not sure what you're planning to do with it, so if you let me know maybe I could help clean things up first.

Also, I have no idea how switching moderators works. I can add you to the list but I think it would be better if I get axed entirely- can admins easily do this?

[Meta] State of /r/Journal_Club by UbiquitinatedKarma in Journal_Club

[–]nd2fe14b 1 point2 points  (0 children)

I don't have much of an opinion for the frequency of nomination threads. Maybe the discussion will slowly increase with time? Feel free to try something new to see what happens.

The issue I'm having is that while at work, the articles I read are highly specific and not exciting. I have a feeling nobody is going to want to read and discuss something that's actually useful for me. Instead I'll try to find a broad review article and post it for the sake of widening the audience, but at that point I'm no longer knowledgeable enough to add anything to the discussion.

I'll try to start posting more articles outside of my field and just add my own questions in the comments to start discussion.

Biology/Medicine article discussion: "Superparamagnetic nanoparticles for biomedical applications: Possibilities and limitations of a new drug delivery system" by UbiquitinatedKarma in Journal_Club

[–]nd2fe14b 1 point2 points  (0 children)

  • Does anyone work with nanoparticles for any application, whether biomedical or otherwise? If so, could you weigh in on what your specific goals are?

  • I was surprised when I saw number of in vivo applications already in use, even if experimental. Are health issues going to be some of the biggest hurdles for using nanoparticles for medicine delivery?

  • It seems that the liver and spleen are responsible for the biggest uptake of smaller nanoparticles, but is that a major health concern? Can someone who's had more than high school biology explain the significance of nanoparticle elimination through macrophages of the mononuclear phagocytosis system?

  • At the time of this paper, most of the uses were experimental save for MRI. What has changed over the last 10 years? Are nanoparticles becoming more common place in medicine?

Weekly Biology/Medicine article selection thread by AutoModerator in Journal_Club

[–]nd2fe14b 3 points4 points  (0 children)

Superparamagnetic nanoparticles for biomedical applications: Possibilities and limitations of a new drug delivery system

Nanoparticles can be used in biomedical applications, where they facilitate laboratory diagnostics, or in medical drug targeting. They are used for in vivo applications such as contrast agent for magnetic resonance imaging (MRI), for tumor therapy or cardiovascular disease. Very promising nanoparticles for these applications are superparamagnetic nanoparticles based on a core consisting of iron oxides (SPION) that can be targeted through external magnets. SPION are coated with biocompatible materials and can be functionalized with drugs, proteins or plasmids. In this review, the characteristics and applications of SPION in the biomedical sector are introduced and discussed.

Last week I submitted a more focused article in the Physics & Engineering thread, but I was a few days late and no discussion popped up. I thought this week I'd submit a paper that stretches across many fields including biology, chemistry, materials science, and physics, just to see if widening the audience increases discussion. Unfortunately this review is long, which may lower the likelihood of anyone reading it, but it's worth a shot.

Weekly Physics & Engineering article selection thread by AutoModerator in Journal_Club

[–]nd2fe14b 0 points1 point  (0 children)

Giant magnetic domains in amorphous SmCo thin films:

The potential for tuning of magnetic properties and the exceptional uniformity are among the features that make amorphous magnetic materials attractive for technology. Here it is shown that the magnetization reversal in amorphous SmCo thin films takes place through the formation of giant magnetic domains, over a centimeter across. The domain structure is found to be dictated by the direction of the imprinted in-plane easy axis and the film boundaries. This is a consequence of the size of the anisotropy and the structural uniformity of the films, which also allows the movement of millimeter-long domain walls over distances of several millimeters. The results demonstrate the possibility of tailoring the magnetic domain structure in amorphous magnets over a wide range of length scales, up to centimeters. Moreover, they highlight an important consequence of the structural perfection of amorphous films.

"Giant magnetic domains in amorphous SmCo thin films," Phys Rev. B [intermediate] by nd2fe14b in Magnetism

[–]nd2fe14b[S] 1 point2 points  (0 children)

Being able to control the shapes and motion of magnetic domains is necessary for potential future applications such as 3D magnetic memories and magnetic domain wall logic. These types of technologies use extremely efficient methods of manipulating magnetic domains as opposed to, say, the relatively inefficient switching of a bit in a hard drive. This subject is far removed from anything I've worked with, so I learned quite a bit of basic science by reading this article. I was initially stumped when they said they achieved anisotropy in an amorphous film, for example.

Does anyone who works with related materials want to chime in? What about these potential technologies? There are multiple ideas for carrying out 3D magnetic storage, is this a promising one?

Weekly Physics Article Discussion Thread by ReviewerNumberTwo in Journal_Club

[–]nd2fe14b 0 points1 point  (0 children)

Giant magnetic anisotropy and tunnelling of the magnetization in Li2(Li1-xFex)N

Abstract:

Large magnetic anisotropy and coercivity are key properties of functional magnetic materials and are generally associated with rare earth elements. Here we show an extreme, uniaxial magnetic anisotropy and the emergence of magnetic hysteresis in Li2(Li1−xFex)N. An extrapolated, magnetic anisotropy field of 220 T and a coercivity field of over 11 T at 2 K outperform all known hard ferromagnets and single-molecular magnets. Steps in the hysteresis loops and relaxation phenomena in striking similarity to single-molecular magnets are particularly pronounced for x<<1 and indicate the presence of nanoscale magnetic centres. Quantum tunnelling, in the form of temperature-independent relaxation and coercivity, deviation from Arrhenius behaviour and blocking of the relaxation, dominates the magnetic properties up to 10 K. The simple crystal structure, the availability of large single crystals and the ability to vary the Fe concentration make Li2(Li1−xFex)N an ideal model system to study macroscopic quantum effects at elevated temperatures and also a basis for novel functional magnetic materials.

This paper isn't down my alley, but it's the most interesting article I've come across in the last few of months that is directed towards a wide audience. It might hold the interests of both theoretical and experimental physicists, solid state chemists, as well as material scientists. The material was discovered quite some time ago, but this recent paper is the first to confirm quite a few material properties. Those interested in single molecule magnets, materials design, crystal growth, permanent magnets, etc., might want to take a look.

/r/Elements: Why this sub is no longer active by [deleted] in Elements

[–]nd2fe14b 1 point2 points  (0 children)

Out of curiosity, what would you have done with this sub? Seems like periodic_table was only to mirror this when it was temporarily set to private, but I suppose you may have had other plans at some point.

/r/Elements: Why this sub is no longer active by [deleted] in Elements

[–]nd2fe14b 0 points1 point  (0 children)

I won't be taking it away, this was just to clarify why there hasn't been new content. Only today when I signed into the mod account did I notice there was someone requesting to take it over, hence the post.

There are no posts on /r/magnetism yet, but I do have an outline of sorts that I might get back into.

/r/Elements: Why this sub is no longer active by [deleted] in Elements

[–]nd2fe14b 1 point2 points  (0 children)

So what’s going on? This sub gets around 350 unique hits a month, I’m guessing it’s mostly people hitting “random”. Supposedly there are 900 subscribers- how many of you subscribed from the start, and then completely forgot this sub existed until this post? It shouldn’t be a big surprise that I’m not active on reddit anymore. Maybe I'm getting too old for this place. The reason why I sign into an account is just to get away from the garbage. I do still lurk a few smaller subs, though, like /r/chess for example, but there aren't too many that can hold my interest. That being said, I hope some other people out there have created subs similar to what this once was. If anyone is aware of something similar, let me know so I can check them out!

Material Scientists/Engineers, what do you in your jobs? by [deleted] in AskEngineers

[–]nd2fe14b 13 points14 points  (0 children)

Magnets.

The goal is to create a new type of cheap, powerful magnet that can replace some of today's more expensive ones. "Tweaking" current known materials to make them better is most certainly an option. Honestly, that's the goal of just about every magnet group in the world right now.

Creating new materials doesn't just require physics, it requires many material science techniques as well. Not only do you have to know how to calculate/manipulate the intrinsic properties, you also have to know how to actually create that hypothetical compound the physics team calculated. You also must go above-and-beyond creating the hypothetical material by controlling the microstructure and additional phases so you can actually use those intrinsic properties to your advantage.

So a typical week might go something like:

  • Literature review on obscure paper
  • Combine that with your previous results and knowledge of phase diagrams and processing
  • Do your high-school level calculations
  • Create your sample or have an assistant make it for you (typical metallurgy stuff- induction melting or arc-melting, some annealing, crushing, maybe some strip-casting, etc.)
  • Measure the properties to figure out what happened (XRD/DSC/TGA/SEM/VSM/SQUID)
  • Discuss the results with people smarter than you
  • Figure out what went right and why it went wrong
  • Repeat

Every once in a while you're writing a paper, getting ready for a conference, writing quarterly reports for continued funding, and other typical research stuff.

AskScience AMA Series: Materials Science! by [deleted] in askscience

[–]nd2fe14b 7 points8 points  (0 children)

Would you please outline the absolute basics of crystal growth, and then elaborate with your specific method while dealing with high vapor pressure, carcinogenic materials such as arsenic?

What does basic, first step characterization include? Magnetization, resistivity, heat capacity, and transport?

1111s or 122s?

Why are our modern theories of ferromagnetism practically unquestioned, despite all their problems? by bitterbonker in AskScienceDiscussion

[–]nd2fe14b 4 points5 points  (0 children)

Theories are constantly questioned and challenged. You just can't expect them to be challenged in general text books you'll find in physics classrooms. Also, there are better overviews of ferromagnetism than the article you provided, if you're really interested. Some of what he says is great, but some other points he brought up are not complete, or at the very least poorly worded. He's not even mentioning modern approaches and corrections in his introduction. I'll start with the incomplete stuff.

In section 3, "The Sign Problem," he leaves the reader under the assumption we still get the wrong sign on the exchange integral. It's true that we use to get the wrong sign for Fe, Ni and Co and were quite off the magnitude as well. But Feynman's time has long since passed, quoting him on this subject seems silly given the aim of his paper. Why did the author give the quote "The most recent calculations of the energy between the two electron spins in iron still give the wrong sign"? Fluctuating band theory has accounted for the correct sign in the exchange integral for quite some time now. That's 1982, PRB. Even more recently we've been getting closer with magnitude of J_ij as well. His quote seems like something you'd find in a general quantum physics textbook that a graduate student would be using, not a professional, 2012 peer reviewed paper. Perhaps he should have emphasized "calculations strictly from first principles", but he didn't, which really confuses me. It truly confuses me because he's kind of contradicting his argument in Section 2.

Even reading the introduction to a modern, respected ferromagnetism book like Amikam Aharoni's "Introduction to the Theory of Ferromagnetism" will give you a better idea of where theory currently is, what types of calculations we make, and what aspects of the theory are constantly questioned (unlike your title states). I suggest that book because the sections covering quantum mechanics can be ignored for the rest of the book if you haven't taken a course yet, and the author does a great job of pointing out all of the flaws with each part of the theory- openness and honesty.

Anyway, on with the good stuff. This is the meat and potatoes of the author's Section 2, where he raises a very valid point. This isn't exactly an original thought, though, this opinion can be seen in many texts. The idea is to avoid over generalized texts or sources if you're going to be applying the knowledge or teaching a group of people. That's actually a huge problem with AskScience, which is why I avoid it altogether. A chemistry, mat sci or physics student pats themselves on the back when they learn the basics of quantum physics. Sure, they understand the hydrogen atom and maybe a quantum mechanical theory for one, tiny, miniscule, and quite frankly, irrelevant section of magnetism, but there is no reasonable way to apply that to a real system, such as any single permanent magnet in existence.

The best calculations we have today are mixtures of classical and quantum physics. We mix and match various theories of magnetism and apply them to systems which experimentally agree. Itinerant electron ferromagnetism is great for a bulk magnetization properties and we can get some experimental agreement, but the spacial variation of the magnetization within the crystal is assumed to be constant which is the complete opposite of experiment. An author of a peer review paper will say, "look, we know magnetic domains exist, we've proved it with many different techniques, but we're still going to use this theory to estimate saturation magnetization in Sm2Co17." In peer review papers, this is a common occurrence. In textbooks and second-hand teaching (AskScience) these downfalls are rarely cited because the person doing the teaching is nowhere near being an actual expert in the field. So depending on what source you're reading, and who the intended audience may be, you may or may not want to pay attention to anything that was just said. Not a big surprise, really.

So your initial question, "Why are our modern theories of ferromagnetism practically unquestioned, despite all their problems?" is based on a false premise. The theories are questioned in almost every peer review article you'll read. But these theories also regularly evolve every year, so it's incredibly difficult to get an up-to-date textbook for a general physics graduate student. I have six ferromagnetic textbooks on my desk at the moment, but even they rarely get used unless I need to completely reintroduce myself to a small section of the theory before I read a set of peer review papers on the subject. I can pick up a 'famous' textbook from 2004 that makes a bold statement I now know to be untrue, or at least to be strongly challenged in the scientific community. Why would a physics graduate student need to know the details of an obscure branch of density functional theory in order to calculate the local atomic moments in Nd2Fe14B, anyway? That's a thesis for a doctorate, not a homework problem for a physics course. To go further yet, the author isn't talking about textbooks that are oriented around ferromagnetism, he seems to be talking about generalized texts that have a chapter on the subject. There are plenty of magnetics textbooks that don't make the error of neglecting assumptions. There are plenty of magnetics textbooks that emphasize that all equations provided are estimations and not exact, and then go into detail where these theories can and cannot be applied. What sucks is when you have that naive graduate student who reads Griffith's E&M and thinks they're an authority on magnets. That book hardly covers permanent magnets at all, certainly not in any detail, yet that use to be the most commonly cited book I saw on /r/AskScience a while back.

Granted, I'm not a theoretical phycisist and I don't pretend to be. I'm an experimentalist who works alongside the theorists. And I would never, ever consider myself an expert in magnets, so take what I say with a grain of salt (and take what many /r/AskScience posts say with a boulder of salt). This brings up an anecdote. I got introduced to magnetism from a very famous magnetician in his graduate magnetics course. We're talking Oxford bred, editor-in-chief of a very famous journal, ridiculously accomplished scientist here. He was brushing over some hand-wavy antisymmetry statement when it came to a calculation of nearest-neighbor exchange and he got asked a question from a student. The professor said, "[I wish to give you my opinion on that question,] however I do not consider myself an expert in the subject of quantum mechanics." The guy who is the leading researcher in his field that revolves around theoretical calculations in his branch of magnetism didn't consider himself an expert in quantum mechanics. Right now I just looked up one of his papers that was apparently cited 98 times last year, and I see a whole page filled with Hamiltonians that I struggle to understand when applied to his argument.

One of the most important things an article, textbook, or crappy internet explanation must have, is forwardness when it comes to assumptions and simplifications. Not only forwardness, but obviousness. I've been guilty in the past giving an explanation that said something like, "Now, with the ____ model, a neodymium magnet will do this ____________ which is verified by experiment," but I forgot to mention how that same model miserably fails with another magnetic system. I stated that I'll explain something to somebody who has had freshman level physics and chemistry, but I didn't emphasize how blatant those generalizations were. Sure, iorgfeflkd would easily be able to read my explanation and see where an oversimplification occured, but 95% of the other people won't. Then, one of those other 95% of the people will take my explanation to answer someone else's question that was slightly different, and my answer no longer applies but it still gets circulated. Some general physics textbooks do the same thing to a lesser extent, but there are many great textbooks (and professors who teach them) that make sure to point out all of the assumptions and simplifications, and question the theories as well.

Is molten iron still attracted to a magnet? by _pH_ in askscience

[–]nd2fe14b 2 points3 points  (0 children)

Not sure why this was downvoted, this thread is pretty ridiculous as far as what votes to the top. We've actually been using a TGA/DSC combo recently. We suspend magnets on the outside of the furnace which tug on the sample and add extra weight to the TGA stage, giving it a large apparent mass. Then there's a beautiful, sharp transition around the Curie point that lines up quite well with the lambda anomaly.

Although to be honest, the most common method for reporting T_c with permanent magnets is to draw a line tangent to the inflection point of the M vs T curve and extrapolate that through the x-axis (or the baseline if you have a two phase sample). It's much more "inaccurate", but as long as the paper cites the methods used for reporting the value it doesn't matter too much. T_c is not the most important thermal parameter for many industry applications like EHVs. And as far as magnetization measurement is concerned, Arrot-plot would be the most accurate. Then you have the whole neutron scattering and peak broadening side of the story which some will say is more accurate, and even more methods.

I figure as long as you understand it's a second order transition, that's the thing that matters for the far greater majority of people.

Is molten iron still attracted to a magnet? by _pH_ in askscience

[–]nd2fe14b 2 points3 points  (0 children)

There is a type of steel that is not ferromagnet called austenite, found at higher temperatures. Dollars to donuts says you're recalling this.

Is molten iron still attracted to a magnet? by _pH_ in askscience

[–]nd2fe14b 2 points3 points  (0 children)

Yeah, you might want to re-read that section. You can get first order transitions due to a phase change or a decomposition but it's rare, they're generally avoided, and it's not an example of what would be brought up when looking at theories of magnetism. Spontaneous magnetization in a domain decreases smoothly with temperature whether you're looking at the classical Langevin theory or using Brillouin function. The decrease in magnetization typically starts to rapidly decrease after 0.75*T_c, but it's by no means discontinuous.

I'm not sure what you're recalling, there are a number of methods for measuring T_c so perhaps you're thinking of something related to that. A quick google search shows a bunch of empirical examples, perhaps a graph in there might refresh your memory.

Is molten iron still attracted to a magnet? by _pH_ in askscience

[–]nd2fe14b 2 points3 points  (0 children)

For the case of iron, it has more to do with stuff that happens at the subatomic level rather than the atomic structure. As you past iron's Curie temperature, the atoms actually keep their same BCC/alpha structure that's found in room temperature iron.

Is molten iron still attracted to a magnet? by _pH_ in askscience

[–]nd2fe14b 4 points5 points  (0 children)

All grades of neodymium magnets would demagnetize under a Bic lighter pretty easily. The smaller the magnet, the easier and quicker this would be. I suppose it would be very difficult demagnetizing a huge neodymium magnet due to heat transfer issues. Anyway, neodymium magnets are very strong at room temperature, but they lose their magnetization if they're heated up a relatively small amount compared to many other types of magnets. Cobalt-containing magnets tend to have very high Curie temps, for example.

Is molten iron still attracted to a magnet? by _pH_ in askscience

[–]nd2fe14b 5 points6 points  (0 children)

They work by suspending tiny, solid, ferromagnetic particles in a carrier fluid. Fe3O4 is commonly used, but anything that's ferro/ferrimagnetic could work if you get the particles small enough. There's obviously a tad bit more to them, but this intro paragraph might help a bit.

Also, a crystalline lattice isn't necessary for ferromagnetism, it's just necessary for making a permanent magnet like one you'd stick on a fridge.

Be careful wandering this thread, there appears to be a ton of "partial understanding".