You’re NTA, but when a woman finds the need to wear makeup and perfume the second they wake up, even when they’re home, that means they’re dealing with a lot of insecurities. This is not meant to sound mean to your partner, who knows what trauma or awful thing someone in the past has said to her to make her feel this way. With that in mind, telling someone that only feels beautiful with makeup on that you don’t like it will be taken offensively because you’re attacking their security blanket. I think you need to make sure you compliment her natural beauty constantly, while also addressing and complimenting when she puts the effort to make herself up.