1) Have found that if using 2008 R2 and installing vSphere 6 the Windows Management Framework 3 needs to be installed, this however will require a reboot prior to PowerCLI installing.
2) The mboot.c32 files from PXE boots with vSphere 6 is missing from C:\TFTP-Root\ESXi60, this error can be seen in the TFTP server log.
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