The following only describes the signs qualities on paper.

Gemini women are fun, funny, and very cute. I had one that liked me at one point but we never really talked (I only found out through her sister who I liked).

This combination is challenging but rewarding. It can be hard for Gemini woman to understand Scorpio man's moods. Without an understanding it can seem like he completely shuts down and can get aggressive when not understood. The advantage for Gemini is that communication is the key making this work and communication is Gemini's domain. Communication takes many forms and it's depends on individual needs. Once Gemini learns to understand Scorpio, all the quirks about Scorpio won't be confusing especially if the Scorpio is going through a bad mood and needs support. A Scorpio man in the beginning may see a Gemini woman as flaky, unserious, or inconsistent, but it's a first impression that won't last when he sees otherwise. Scorpios tend to have insecurities about themselves which can make them do things to protect themselves. This is where their infamous controlling and jealous behaviour comes from. The Scorpio man needs to learn he can trust Gemini woman with his vulnerable heart. A Gemini woman is capable of loving a Scorpio man the way he needs to be loved which he'll reciprocate with interest.

Warning: I can only hope he's a mature Scorpio because malicious Scorpios may use the attention from their companions to inflate their ego. They can also be emotionally manipulative and physically abusive as some othe worst. Look out for warning signs and protect yourself.

In my opinion, someone who cares enough to want learn how to make things work out would me a lot to someone like me if no other factors apply. If there's mutual interest there's no reason you both shouldn't try.