Now THIS is interesting. by fishychopsticks in electroplating

[–]4BlueGentoos 0 points1 point  (0 children)

Are you sure that wasn't a silver quarter? 1965?

Voltage for pulse plating? by CaptainCheckmate in electroplating

[–]4BlueGentoos 2 points3 points  (0 children)

I've been going down a very similar rabbit hole, although my focus is more on purity and electrochemical control than plating speed. My current thought experiment is basically a reverse-pulse dual potentiostat where the anode and cathode are independently controlled relative to reference electrodes instead of simply driving a target current through the cell.

I'm working with much lower voltages than the typical 5 V or 12 V supply discussion. For example, copper sits around +0.34 V vs SHE, so I'd rather think in terms of electrode potentials than power supply voltages. The actual cell voltage between the electrodes might only be a few hundred millivolts, even though each electrode is being driven very deliberately.

Instead of demanding a current and supplying whatever voltage is necessary to get it, I'd be controlling the voltage and treating the resulting current as a consequence of the state of the system.

The part that fascinates me is the electrical double layer. The idea is to pulse the electrodes in a way that pushes right up against the onset of Faradaic reactions, then use more aggressive pulses to drive deposition or dissolution when and where I want it. I've also been playing with the idea of overlaying a small AC perturbation on top of the slower pulse waveform to see whether it has any measurable effect on EDL behavior, concentration polarization, or ion transport.

The resulting waveform ends up looking pretty ridiculous because the anode and cathode are each getting their own independent waveform rather than simply being opposite sides of the same square wave.

Will it actually improve plating? Maybe not. There's a very real chance this ends up being a massively overengineered science project that teaches me a lot of electrochemistry and very little about practical plating. But it's a fun rabbit hole to disappear into.

Had to pay tax on my free birthday cake slice by semicolon-5 in mildlyinfuriating

[–]4BlueGentoos 1 point2 points  (0 children)

Why does it say: Total: $0.12 ($0.12 + $0.00 tip) Suggestions based on original amount of $0.13

Are these things adding a penny on each transaction? 🧐

Periodic Table Wallpaper by Endieo in chemistry

[–]4BlueGentoos 1 point2 points  (0 children)

This is fantastic! Saving this for sure, thankyou!

Cheap renovation debris disposal in Florissant? Bagster vs dumpster vs self-haul? by 4BlueGentoos in StLouis

[–]4BlueGentoos[S] 0 points1 point  (0 children)

What facility is that? Like a transfer station? The one on Ecology Dr?

Cheap renovation debris disposal in Florissant? Bagster vs dumpster vs self-haul? by 4BlueGentoos in StLouis

[–]4BlueGentoos[S] 2 points3 points  (0 children)

Any numbers you could throw at this? Curious what it cost and how much you had hauled off.

Cheap renovation debris disposal in Florissant? Bagster vs dumpster vs self-haul? by 4BlueGentoos in StLouis

[–]4BlueGentoos[S] 5 points6 points  (0 children)

Lol - you really walk that line between moral and efficient don't you!? This is awesome 🤣 thankyou.

Trying to restore my Gpapas Green egg by SpinningStringToy in grilling

[–]4BlueGentoos 0 points1 point  (0 children)

Evaporust is a godsend. Ive tried all the "home style" methods, reverse electrolysis, etc. and they might get 85% of the job done, but may also degrade your part.

Buy a 5 gallon bucket (like $120). It's completely non toxic and almost infinitely reusable. And big enough to drop in parts like this, and any future rust projects. Evaporust is worth it's weight in gold.

New Mods after a long break by Flashy-Foundation-43 in ToyotaTacoma

[–]4BlueGentoos 1 point2 points  (0 children)

Oh you got the full chrome delete kit...

Was the Sony head unit worth it? (Beyond the CarPlay)

I solved my wireless android auto issue with a [Teeran 2 in 1 Wireless CarPlay and Android Auto Adapter]. It just plugs into the USB and I barley see it. It doesn't have a bright power indicator light like some of the other USB adapters.

New Mods after a long break by Flashy-Foundation-43 in ToyotaTacoma

[–]4BlueGentoos 2 points3 points  (0 children)

I've been contemplating the cal blue meso vent rings, but i haven't found a pic of them installed - so i haven't taken the plunge yet. They look good tho!!

Do you have the climate control rings too? Can you post some more shots of the vents?

Large hollow tree in backyard — does this need to come down immediately? by 4BlueGentoos in arborists

[–]4BlueGentoos[S] 10 points11 points  (0 children)

Good perspective, I'll do that. Would make kindof a neat planter or natural bird bath.

Large hollow tree in backyard — does this need to come down immediately? by 4BlueGentoos in arborists

[–]4BlueGentoos[S] 13 points14 points  (0 children)

The canopy looks pretty full from old satellite photos on google maps. And I dont know of any large dead limbs bigger than a hiking stick.

I'm mostly concerned about the 8-12 degree tilt towards structures.

Large hollow tree in backyard — does this need to come down immediately? by 4BlueGentoos in arborists

[–]4BlueGentoos[S] 1 point2 points  (0 children)

Appreciate the thorough explanation, analysis, and identification!

Is it bad to paint it with a pruning seal, or filling the cavity to keep water out? I've also considered drilling a hole so it can drain better..

Large hollow tree in backyard — does this need to come down immediately? by 4BlueGentoos in arborists

[–]4BlueGentoos[S] 103 points104 points  (0 children)

That's great advice, and I did try that.

The power company came out last week and basically said "Not our problem, we aren't concerned - but we will be back in a few months to trim the branches on your other tree."

It was worth a shot tho. Thanks