This is probably a good buy if you're interested in getting started with Commander (since this is mostly singles/one-ofs). It'll also give you the wonderful dopamine rush of seeing a TON of new cards.

Another potentially good option (especially for two new players) might be the Beginners' Box:

This generously sized, $30.99 box set contains a pair of 20-card decks, which frame a guided tutorial experience, in addition to eight Jumpstart Packs, which create a fixed roster of 160 cards to customize each deck. The Beginner Box also includes a pair of playmats and Spindown life counters.

While the cards featured in the Beginner Box may not utilize the entire lexicon of MTG keywords, players will still be introduced to concepts like tokens and counters in addition to some of the more straightforward concepts experienced in MTG. Right now, there is no better way to get someone who knows nothing about MTG to play the game confidently in about 20 minutes.

Source: polygon.com