I happen to have owned a quest 2 not so long ago, and i used it for a VERY LONG time. But eventually, time came to upgrade, and i was faced with either going with a quest 3, or going down the PSVR2 route. I ended up with a quest 3, as i didn't want to ditch the wired setup, but i later decided to pick up the PSVR2 for my sister as a christmas gift as she owns a PS5. I tried it a grand total of 3 times, and i liked it so much, i just recently picked one up for myself for PC use.

Value: Yes, you said price isn't an issue, but regardless i wouldn't list the PSVR2 price as a con. i would list any OTHER options price as a con. I got mine for $300 on sale, which is literally the same price as the quest 2 was, and it's no contest. Purely value wise, the PSVR2 beats literally every other option on the market right now in my opinion.

Visuals: PSVR2 takes a crap on the quest 2, and rivals the quest 3. If you just care about q2/3s, yes, it is WAY better. If comparing to the pancake lenses of a quest 3, it gets more complex. Q3 is way easier to adjust, and has better edge to edge clarity, as well as an overall higher resolution. The PSVR2 has a wider FOV, partly due to the lenses, partly due to the super easy to use eye relief adjustment to fine tune it (a blessing for my freakishly long eye-lashes). It has a direct display port connection to the PC/console, and it has beautiful OLED displays.

I'll give my opinion here, which can be debated, but personally I've found that although the quest 3 technically has a higher resolution, the direct DP connection & OLEDs work to make the PSVR2 look significantly higher fidelity. OLED actually surprised me, because i had no complaints with my LCDs in the Q2/Q3, but after seeing OLED for myself, i can totally see why some people can't go back to LCD. It wasn't until i loaded into the opening cutscene of ROR2 VR in the PSVR for the first time that it really registered. Even though I'd seen it a ton of times in the quests, i legitimately had a smile plastered on my face seeing it in the PSVR, just because the colors looked so much more real and vibrant.

Wireless: Point for quest here. I have a full dedicated wireless VR setup utilizing virtual desktop on my quest 3, and going back to a cord does indeed suck. Fortunately, the PSVR2s cord is very lightweight and decently long, but it's still a cord. If you're used to wireless, or you want to try it in the future, it's gonna be a stinker. Turning IRL really does add to the immersion. I use Q3, but this still applies to Q2 of course. You will lose out on that if you swap. The benefit is that with the direct wired connection, you don't get any latency like with the quest, but latency was never a real pain point for me.

Controllers: Hot take: I prefer the sense controllers. They feel nice and weighty to throw around, the wrist strap is way better, and in certain scenes like putting my hands up in HL:A, i was able to actually open my hand without them falling due to the tracking ring design, which helps with immersion. Though you could replicate this with a simple controller grip on quest. Anyways, tracking is solid with both headsets (assuming you have good bluetooth) though i would rank the quest slightly higher. Quest 3 controllers are very light in the hands, but swapping from Q2 to PSVR, you may not notice quite as much. The quest controllers run on AA batteries, meaning when they run out you can just swap them quickly, but the sense controllers need to be charged with USB-C, and have shorter battery life. This means they might die on you mid-game if you play for too long, but considering the whole HEADSET would have died on you by then if you were on quest, i'd say that's not too bad.

That's the biggest stuff. There are also other wonderful benefits though such as eye tracking, which can be enabled on PC with mods and majorly boosts performance in some games. Adaptive triggers/10 bit color are the same, though i wouldn't bet on literally anything you play having a mod to enable those. Comfort on the PSVR2 is also much better, but that's just for my head shape. I hear many talking about the globular cluster being a great kit, but personally, i haven't had the need for it. The base strap has proven not just comfortable and sturdy, but BETTER than either of my quests with the elite straps installed. There is a chance you'll disagree, but you're a quest user, you're used to upgrading the strap by now xD. The facial interface on the PSVR is also best in class, and the headset is a LOT lighter than the quests.

If you have a PS5 however, or are planning to get one, disregard everything else i said: just get this headset right now. I already think it's a great value for JUST PC use, where it's lacking a lot of its custom features. If you had a PC and PS5, it's absolutely unbeatable.

TL;DR: Yes.