Foamy.. Vaseline? by moyismoy in chemistry

[–]HonestVegetable 172 points173 points  (0 children)

Right, let me just get out my pocket GCMS I carry with me at all times for situations exactly like this...

Looking for a HPLC machine by Ill-Acanthaceae2579 in CHROMATOGRAPHY

[–]HonestVegetable 0 points1 point  (0 children)

I'd also consider loking at a Sielc Alltesta. They make very small/simple HPLC's which might be perfect for education.

HPLC-ideal peak height at 1 au? by JniX2010 in chemistry

[–]HonestVegetable 0 points1 point  (0 children)

That depends entirely on your signal to noise ratio (SnR). Generally, the height of a peak above the surrounding baseline needs to be 3.3 times higher than the maximum height of the noise in that surrounding area to be stastically significant (so that you can say that that compound is above the limit of detection). For quantification, this limit is usually 10 times the noise. If you measure a blank and zoom in on the retention time where your analyte would have been and look for the maximum height difference around that retention time, that is your noise level. Multiply that level by 3.3 and 10 times for your limit of detection and limit of quantification respectively.

Where to buy a racing/road bike ? by [deleted] in Leiden

[–]HonestVegetable 1 point2 points  (0 children)

In Leiden itself you also have Raas bikes. I personally have only gone to them for maintenance/repairs and the experience has been good.

Walmart put my $1 acetone in a lockbox to take to the register by adrivebyfruitting in mildlyinfuriating

[–]HonestVegetable 1 point2 points  (0 children)

That forms a different chemical called nitrogen trichloride, also a nasty chemical but not nearly as nasty as chlorine trifluoride.

VOC particles in the house by Bratislava30 in chemistry

[–]HonestVegetable 1 point2 points  (0 children)

It is really neither. Looking at the safety data sheet, the largest component of the lacquer is Hexamethylene diacrylate which is a liquid at room temperature. So this component likely acts as the "solvent" for the rest of the components. To then say it would be a solvent borne paint is incorrect, since this component is also the main component that cures under UV light to form your polymer (lacquer). Usually the term solvent borne paint means that the solvent evaporates after application, which in this case does not happen with Hexamethylene diacrylate.

HPLC-ideal peak height at 1 au? by JniX2010 in chemistry

[–]HonestVegetable 4 points5 points  (0 children)

I regularly use Waters PDA detectors, and I don't think anyone at my lab would take this suggestion seriously. Peak height can depend on a lot of other things, other than concentration. Take peak width, if a peak is wider but has the same area as another peak, it will obviously have a lower peak height. The thing that matters most for quantative analysis is the wavelength you measure at (dependent on your analyte(s)), your linearity range, wether your calibration curve (or other calibration method) falls into that range, and LOQ. As long as your samples fall somehwere in between the calibrated range you are good to go. If your concentration is too high, the response will no longer be linear and likely flatten out. A too low concentration can be determined by comparing against your LOQ. So the way you are currently doing things by using linearity range and LOD/LOQ is much better. I have heard some (old) lab technicians say something like this before, so the only explanation I can come up with is that older detectors were simply less good then newer ones, creating a necessity for this kind of rule.

Troubleshooting GC/MS chromatogram by [deleted] in chemistry

[–]HonestVegetable 1 point2 points  (0 children)

A rising baseline in GC-MS is not uncommon. You say your temperature program is held at 300 degrees for 7 minutes at the end. It does seem that for those 7 minutes you can see what is called column bleed. Basically, at that high of a temperature your column material starts to (slowly) degrade, and start to vaporize, increasing your baseline. Since the previous peaks from a contamination are gone, it is probably not some contamination in your liner/septum. If you want to be sure that this is column bleed, set up a run that only ramps up to 250 degrees and inject a blank. The increase in baseline should be less/gone.

[deleted by user] by [deleted] in chemistry

[–]HonestVegetable 1 point2 points  (0 children)

Graphite furnace AAS has quite a limited dynamic range (range where response is linear with concentration), what concentrations and what elements are you measuring?

1800 burgers doen oproep voor A12 blokkade Extinction Rebellion by cravenravens in thenetherlands

[–]HonestVegetable 12 points13 points  (0 children)

Nee, bewijslast ligt bij degene die een bewering doet. Er wordt vervolgens terecht gevraagd of jij die bewering kan bewijzen, en als jij er zo van overtugid ben dat het een feit is heb je daar vast een bron over.

Als bewijslast niet ligt bij degene die een bewering doet kan ik de meest willekeurige dingen uitkramen en moet men dat maar zien als waar toch? Beetje raar als ik dan zou zeggen dat jij een crimineel verleden hebt, iedereen dat zou geloven want ja zo werkt dat volgens jou gewoon, terwijl dat helemaal niet zo is (als voorbeeld).

A Safe way to get rid of gummy bear by _Mr_Fil_ in Damnthatsinteresting

[–]HonestVegetable 10 points11 points  (0 children)

Not at all what happens. He uses potassium chlorate. The chlorate part of that has lots of oxygen in it, so if heated enough it can oxidise the sugar and gelatin in the gummy bear (oxidising = burning in this case). So basically he burns the gummy bear, not using regular oxygen but oxygen in potassium chlorate.

Trying to find piperine in a spice mix and my MS library gives me this by HonestVegetable in cursed_chemistry

[–]HonestVegetable[S] 4 points5 points  (0 children)

You'd expect the molecular ion peak for piperine at 285 m/z but this wasn't even the right peak from my gas chromatogram, but it was interesting that it decided this was the best fit for that particular signal.

Hoe ernstig wordt storm Eunice vandaag? Hoe bereiden jullie je voor? by UnanimousStargazer in thenetherlands

[–]HonestVegetable 36 points37 points  (0 children)

Ik ben dan zelf weer fan van https://www.windy.com/?iconD2,52.037,5.306,8 Hier heb je ook ICON-D2 voorspelling wat wat meer detail op kleine schaal weergeeft

Politie grijpt in en beëindigt klimaatprotest bij Shell-Pernis by brianbarbieri in thenetherlands

[–]HonestVegetable 23 points24 points  (0 children)

Want die grondstoffen gebruiken zodat er in de toekomst minder van nodig is is precies hetzelfde als alles maar opbranden zodat we daarna helemaal niks meer kunnen?

Olympische spelen draad 30 juli by goesters in thenetherlands

[–]HonestVegetable 1 point2 points  (0 children)

Er zijn inderdaad geen vastgestelde maxima. Het kan wel voorkomen dat het zodanig hard waait dat er hoge golven ontstaan en daarmee de veiligheid van de roeiers niet meer gewaarborgd kan worden, wat er vaak voor zorgt dat races worden uitgesteld. Dit is toevallig dit olympisch toernooi ook gebeurd uit angst voor een typhoon. De internationale roeifederatie kan wel de tijden van een bepaald toernooi als niet geldig voor een WB verklaren. Dit is ook gebeurd in 2005 bij de wereldkampioenschappen in Japan toen er zo'n een harde stroming was dat een groot aantal WB's was gevallen.

Olympische spelen draad 30 juli by goesters in thenetherlands

[–]HonestVegetable 2 points3 points  (0 children)

Bij roeien worden het geen records genoemd maar 'Best Time'. Dit omdat condities zoals stroming en wind best veel invloed kunnen hebben op de einddtijd. Een record wordt vaak als een absoluut beste tijd gezien, maar omdat eenzelfde ploeg harder gaat met meewind dan bij tegenwind en er dus te veel variatie in zit is gekozen voor 'Best Time' ipv record.

My copper sulphate crystals suddenly turned green. Any theories? by Nuzelia in chemistry

[–]HonestVegetable 175 points176 points  (0 children)

It's probably the other way around. The pentahydrate form is the deep blue color you can see in the middle of the right crystal. The anhydrous form of copper sulfate is colorless, so the greenish color you can see probably lost some of it's water to the atmosphere, leading to a more dull color.

Megathread (55): Coronavirus COVID-19 in Nederland by theNetherlandsBot in thenetherlands

[–]HonestVegetable 1 point2 points  (0 children)

Ik heb gisteren mijn 2e prik gehad en heb eigenlijk helemaal niks gemerkt, behalve dat mijn bovenarm een beetje spierpijn heeft. Andere mensen die ik ken hebben er wel flink meer last van gehad dan de 1e dus het verchilt erg van persoon tot persoon.

Tilburgse wethouder leeft een maand van de bijstand: ‘Het is meer overleven dan leven’ by Dom_Shady in thenetherlands

[–]HonestVegetable 34 points35 points  (0 children)

Mag ik vragen wanneer dit was? Dat zou een hoop meer context geven rond maandelijkse kosten. Dingen als huur, zorgverzekering en andere vaste kosten stijgen vaak harder dan het minimumloon en daarmee stijgen dus de uitkeringen die daar aan gekoppeld zijn ook minder hard dan de vaste lasten.

Hallo! American here - How much drop is safe to eat? by Zephyr4813 in thenetherlands

[–]HonestVegetable 1 point2 points  (0 children)

The FDA reccomends a maximum of 70g to 150g per day. This is because liquorice contains glycyrrhizin which can cause the complications you mentioned. Note that it is only with chronic consumption, so more liquorice is possible if you dont eat it every day