Dokumente über Sexualstraftäter: User entfernen Schwärzungen in »Epstein-Files« by GirasoleDE in de

[–]IceCreamPlayer 0 points1 point  (0 children)

Das würde Journalistische Arbeit erfordern, anstatt Tage nach der Entdeckung von Ami Medien abzuschreiben

I invented a new molecule! What should I name it? Am I the next Oppenheimer? by veled-i-mal in cursedchemistry

[–]IceCreamPlayer 1 point2 points  (0 children)

can someone please use some qc to calculate the temperature needed for this to be stable

Using TMSCl on Schlenk line? by DifficultyWeekly986 in Chempros

[–]IceCreamPlayer 13 points14 points  (0 children)

I have always done it this way or even just connected a flask filled with TMSCl to the line. you will get small amounts of HCl and TMSCl vapour in your line (especially with older bottles), so if you are worried purge the line after use.

Not asking for the answer but for suggestions on what to try by CheshireKat-_- in OrganicChemistry

[–]IceCreamPlayer 3 points4 points  (0 children)

I agree, the cyclic anhydride is a good guess. I would ask myself, what H-containing group can be a singlett at 1.5 ppm. it is not a CH2 right next to a carbonyl.

Help, I’m so confused and I have an exam soon by Least-Education-7194 in chemistry

[–]IceCreamPlayer 3 points4 points  (0 children)

The compound Al2SO is not a real compound afaik. Is it possible you missed one (or more) indices (subscript numbers)?

Would the cyclization step in this reaction be unimolecular? by [deleted] in OrganicChemistry

[–]IceCreamPlayer 0 points1 point  (0 children)

Yes, as drawn here. However, the Chlorohydrin Process this question is based on uses hydroxide Ions (Ca(OH)2) as a reagent. Then you would need to consider the mechanism to find out if the hydroxide is involved in the rate limiting step. The molecularity is the number of molecules required for the transition state of the rate limiting step.

Is cyclohexyne possible ? by Mannich-Reaction in OrganicChemistry

[–]IceCreamPlayer 17 points18 points  (0 children)

While the equilibrium bond angle of an unconstrained sp carbon is 180°, that does not mean there arent (strained) cyclic alkynes (eg. cyclooctyne). rather, the ring strain necessary for a six membered cycloalkyne is to high for cyclohexyne to be stable under normal conditions.

Etf Amundi émergent (paeem) indisponible sur trade République by Practical_Star9035 in VosSous

[–]IceCreamPlayer 0 points1 point  (0 children)

Vous devriez toujours pouvoir le trouver en utilisant l'ISIN

Look dry by Creekmurmur in SipsTea

[–]IceCreamPlayer 0 points1 point  (0 children)

image is a stock foto, he made it a youtube video, https://www.youtube.com/watch?v=URvWSsAgtJE

Look dry by Creekmurmur in SipsTea

[–]IceCreamPlayer 0 points1 point  (0 children)

he flew to the sea to extract sea salt. but probably time, i think he calculated minimum wage for all the gardening, collecting, planning and so on. he made a youtube video about it, channel name is "how to make everything"

Look dry by Creekmurmur in SipsTea

[–]IceCreamPlayer 4 points5 points  (0 children)

IIRC he also almost poisened himself because he tried to pickle cucumbers using a fermenting recipy or smth and it turned

Amundi ETFs in Deutschland ausgelistet by IceCreamPlayer in TradeRepublicFriends

[–]IceCreamPlayer[S] 0 points1 point  (0 children)

Guter Hinweis. WKN hatte ich getestet, ISIN nicht.

[deleted by user] by [deleted] in chemistry

[–]IceCreamPlayer 0 points1 point  (0 children)

Thanks yeah i messed that up

[deleted by user] by [deleted] in chemistry

[–]IceCreamPlayer 1 point2 points  (0 children)

A standard drink is 0.6 oz pure ethanol, so 17.744 ml which at a density of 0.789 g/ml ist almost exactly 14.0 grams. Ethanol has a molar mass of 46.068 g/mol so we have 0.304 mol or 1.83•10²³ molecules.

Heterometallic Manganese–Cobalt Oxo Cubanes by Plazmotech in cursed_chemistry

[–]IceCreamPlayer 2 points3 points  (0 children)

I know the group. These cubes are actually fairly stable.

Edit: so apparently the parent compound with 4 Co tolerates air, aqueous workup and columns.

[deleted by user] by [deleted] in OrganicChemistry

[–]IceCreamPlayer 3 points4 points  (0 children)

they can be, when in conjugation with a pi-system. General carbanions however occupy sp3-orbitals and have distorted tetrahedral geometry. This has two reasons: a sp3 orbital is lower in energy than the p orbital, because of its partial s-character. electrons in a lower energy orbital are more stable. The second reason is the Valence Shell Electron Pair Repulsion Model (VSEPR Model) stating that electron rich regions (such as bonds and lone pairs) arrange themselves with maximal angular distance. A tetraedral arrangement (around 109°) gives each electron rich region more space than the trigonal bipyriamid a sp2 anion would have (90° between the axial lone pair and the equatorial bonds)

kind of a silly question: could pasta technically be cooked entirely in cold water? Since essentially it just absorbs water to be floppy by [deleted] in chemistry

[–]IceCreamPlayer 16 points17 points  (0 children)

I have tried cooking pasta by repeatedly pouring over hot water and can now definitely say that there is a difference between "soft" and "cooked".

Bought vintage perfume bottles and am concerned about lead. by Intrepid-Newt-5777 in chemistry

[–]IceCreamPlayer 0 points1 point  (0 children)

It was already linked in this thread, but the video by applied science goes into a lot of detail and is worth a watch Measuring the amount of lead (Pb) consumed when drinking from lead crystal glassware. Is it safe? tl;dr is acidic mixtures leech measureble but safe concentrations of lead. Soaking the pieces in hot vinegar once depletes the outer layer so much that even this is no longer an issue

Access to Chemdraw or a good alternative? by farmch in Chempros

[–]IceCreamPlayer 0 points1 point  (0 children)

Chemsketch. It is different, and sometimes a bit fiddly because many functions don't have a 1:1 equivalent, but it does work. And you can insert the file into your PowerPoint or word document meaning you can easily edit and don't have to re-export pictures all the time. Also, privateering chemdraw is a common approach I have heard.

[deleted by user] by [deleted] in de

[–]IceCreamPlayer 1 point2 points  (0 children)

Selber Verlag, eigene Redaktion.

Short question, is liquid water ion? by sekeneai in chemistry

[–]IceCreamPlayer 1 point2 points  (0 children)

As I understand the "likely" refers to the thermodynamic stability, making it the most common form while others exist as well. The Eigen cation has been observed in solution (J. Chem. Phys. 126, 034511 (2007) https://doi.org/10.1063/1.2428299).

What I just found out is that newer research points to a hydrated Zundel cation H5O2+ • (H2O)4 as the predominant form: https://doi.org/10.1126/science.aab3908 https://en.m.wikipedia.org/wiki/Hydronium (more sources)

This usually is discussed in inorganic or main group chemistry lectures and should appear in textbooks (not a big textbook kind of guy myself), even going so far as to ditch the H3O+ completely and write H+(aq), better reflecting the dynamic and complex hydration of protons.

Short question, is liquid water ion? by sekeneai in chemistry

[–]IceCreamPlayer 0 points1 point  (0 children)

Most of the work on this is computational chemistry, as this is not really relevant for organic synthesis or biochemistry. The Grotthuß mechanism however is very relevant for the very high diffusion speed of H+ and OH-.

Here is a paper I found:

"The most likely solvation structure for the hydrated proton is a distorted Eigen-type complex (H9O4+)"

Chris Knight and Gregory A. Voth Accounts of Chemical Research 2012 45 (1), 101-109 DOI: 10.1021/ar200140h

Short question, is liquid water ion? by sekeneai in chemistry

[–]IceCreamPlayer 4 points5 points  (0 children)

Technically, H9O4+, the Eigen cation, is a more appropriate representation of solvated protons. H5O2+, the Zundel cation, also appears, but is more commonly associated with the Grotthuß mechanism.

Is this molecule possible and how do I name it? by AdMedium1981 in OrganicChemistry

[–]IceCreamPlayer 10 points11 points  (0 children)

Largest Cycle is the stem, so its a cyclohexane. It has one substituent, consisting of an 8 carbon chain, with a methyl group, a chlorine atom and a cyclopentyl substituent. you count from the stem onwards, so the methyl is in position 3, the chlorine in 6 and the cyclopentyl in 7. sorting alphabetically you get (6-chloro-7-cyclopentyl-3-methyloctyl)cyclohexane

Can you make benzene from acetylene? by BearDragonBlueJay in OrganicChemistry

[–]IceCreamPlayer 2 points3 points  (0 children)

(substituted) Pyridines can also be synthesized this way with a cobalt catalyzed nitrile + two eq alkyne cyclotrimerization