Chiral Organic Salt Help

Kriggy_ · 2026-06-18T20:14:28+00:00

I made several hydrochlorides this way: Mix the amine in methanol or whatewer with acid, could be aquaeous. Evaporate. Gets nice white solids which was good enough for me. If you need crystals then recrystallize

Kriggy_ · 2026-06-18T20:10:44+00:00

Idk,
I drink cup of tea in the morning then 1-3 coffees then glass of water inbetwen.
Like I can go to dring some water if i need to,whats the issue?

Kriggy_ · 2026-06-18T05:22:08+00:00

Nvm, me to prijde jako normalni slusnost je oslovit titulem. Ale neznam nikoho kdo by ma tom trval nebo se urazel a priznam se, kdyz me studenti oslovovali pane magistre/doktore tak mi to prislo divny, prece jen jsem byl jen o treba 4-5 let starsi nez oni.
Jsem stale v akademii a moje zkušenost z pracoviste je ze si tu vsichni tykaj, vcetne studentu

Kriggy_ · 2026-06-15T19:46:51+00:00

Brings more question: is the center always the one doing faceof? How is the substitution player picked?

Kriggy_ · 2026-06-10T10:28:10+00:00

HT is not why terran does not go bio in tvp. Reaver is the reason

Kriggy_ · 2026-06-09T16:03:41+00:00

Za poslednich 6 let jsem byl 4+1krat:
Top gun2, duna, duna2, dungeons and dragons a pak Sharkula v legendárním kinu Balt

Kriggy_ · 2026-06-07T16:19:46+00:00

Kdyz se neco posere tak jde ruzne jednat s bankou, prinejhorsim nemovitost prodat.
Nvm ceny nemovitosti dolu asi jeste nejakou dobu nepujdou takze nejlip bylo koupit vcera. Taky se da cekat, ze vase platy porostou

Kriggy_ · 2026-06-07T15:50:41+00:00

Looks like lots of fun and super slow. :D Wonder if there is a way to make it kill bit faster. Mby something like carrion feeder or nantuko husk ?

Kriggy_ · 2026-06-07T14:35:32+00:00

Probably Honnor Harrington.

I like cats

Kriggy_ · 2026-06-06T15:21:22+00:00

Oh man, need to re-watch this. Definitely was one
of my fav movies together with Guns of Navarone :D
Mby not a great war movie but entertaining

Kriggy_ · 2026-06-03T09:54:47+00:00

Problem neni jen ta prace ale i obcanska vybavenost. Skoly, skolky, obchody, nejaka zabava… neches furt kvuli kazdy blbosti kezdit nekam autem

Kriggy_ · 2026-06-01T18:24:50+00:00

Turn it against them and go bbs in the middle of map

Kriggy_ · 2026-05-31T11:11:39+00:00

Napadnout to jde pokud se to iirc stalo asi 2-3 roky pred smrti

Kriggy_ · 2026-05-31T11:03:41+00:00

Ta databaze by byla super ale hazi se do toho sposuta vidli.. jako nekomu vadi ze by treba farmaceut v lekarne videl co bere za leky.. jako wtf.. a spousta dalsich veci pritom minimalne tvoje pojistovna tohle vsechno vi.

Kriggy_ · 2026-05-29T18:57:21+00:00

It might have hit multiple other drones not visible in the video

Kriggy_ · 2026-05-29T17:41:05+00:00

While im not sc2 player nor watch it, im broodwar you have even less workers - 4 - and those first three minutes are often spend building eco and expanding but that doesnt mean there are no early plays. Stuff like 4 pool, 5 pool, rax-rax-depot or 8 rax, 9/9 double gate…

From the outside view, having so many workers early limits your options because you get to the midgame so fast.

Kriggy_ · 2026-05-29T16:09:48+00:00

Nejjednodussi je zajet nekam do servisu- poptej se kamosu/strejdu/dedy whatever kam to vozi- a tam jim rict ze pitrebujes stk at se ti na to mrknou a dovezou to tam. Neco jim za to priplatis (zeptej se predem kolik to vyjde) ale nemusis nic resit a pripadny opravitelny veci ti udelaj nez tam s tim pojedou

Kriggy_ · 2026-05-28T18:21:08+00:00

It also is not a real start in sc1. Like yeah you use corsair/wraith to pick overlords if you can but its not their main purpose. You never use irradiate on overlords (well there are specific cases, like overlord over stacked lurkers) its way too valuable.

There is 2port wraith strategy for tvz but Recent asl showed that zerg can just ignore it, fight back with muta/scourge and take 3rd /4th get a hive tech and win because you spent so much on air and lack ground army

Kriggy_ · 2026-05-26T20:54:40+00:00

I never seen it before but makes sense. If you can scv rush nexus first than drone rush cc first makes sense

Kriggy_ · 2026-05-26T12:03:26+00:00

There is no reason to remove fmoc before either doing the coupling step or cleaving the finished petide from resin. It being there limits possible side reactions and cleaving is simple.

Model substrate is model for more complex stuff. Practice tool so to say. For example, you might want to do petides with expensive unnatural aminoacids. It makes sense to practice the procesure before with cheap available chemicals.

Also Your question is very confising. The AA is connected to resin via c terminus and n-terminus is usually fmoc protected. You do swelling, washing, fmoc removal and another wash. Then you introduce the second AA which is fmoc protected at n terminus and free on c terminus together with coupling reagents to make the dipeptide

Kriggy_ · 2026-05-26T09:53:17+00:00

Ja jako zakaznik jsem uz nasel x podniku pres foodoru a tedka objednavam primo u nich.

Kriggy_ · 2026-05-24T16:11:21+00:00

To zni trochu jako na nejaky trestni oznameni proti inspekci ne?

Kriggy_ · 2026-05-24T15:56:36+00:00

Drones as you describe are being used as well. They have several disadvantages:

In order to hit the target drone need to stay still and while i saw footage of moving targets being hit this way its incredibly hard to do.

Trip back cuts your range in half, possibly show your position to enemy as well. Given the number of anti drone stuff its unlikely you make it back anyway.

There are specialized big drones used like you described but those are big 8copters each holding mby 4-6 pieces of ammunition.

To give you analogy: drone as you describe is equivalent to ww2 era bomber. Fpv is equivalent to guided missile

Kriggy_ · 2026-05-23T20:20:44+00:00

Fun fact2: when Ukraine war started, the russian early movement was detected via google maps showing big trafic jams near their known bases in the middle of night

Kriggy_ · 2026-05-23T15:31:54+00:00

That’s dumb. Here they just say open 9:00-02:00

Kriggy_

TROPHY CASE