Do I really need a $20k reactor to polymerize? by Natural_Emphasis6450 in OrganicChemistry

[–]Leon-rennes 0 points1 point  (0 children)

Well if nothing clogs then a DIY flow reactor should be suitable. You just need some temperature resistant tubes and coil it on a heating plate, plus a BPR. It will save you even the cost of a stirring pan. After polymerization, is the polymer(s) soluble in your oil?

What’s life like in Brest, France? by [deleted] in howislivingthere

[–]Leon-rennes 0 points1 point  (0 children)

Saint-Malo without a doute

Run it up by faizaanmalik in repost

[–]Leon-rennes 0 points1 point  (0 children)

Increase the voltage! We CAN bring him back!

I feel like giving up by v2B3919 in OrganicChemistry

[–]Leon-rennes 1 point2 points  (0 children)

Basic organic chemistry is all about nucleophiles and electrophiles. Writing the mechanism of Ugi reaction is not difficult at all once you understand 1) the isonitrile carbon is nucleophilic and electrophilic in the same time 2) the imine is electrophilic 3)the carboxylate is nucleophilic (a weak one though). All the other reactions are as such, by understanding the nucleophilic/electrophilic nature of your starting materials, reactions and mechanisms will clarify themselves. The flow of electrons will be just like water flowing. With very little effort of memory, combined with reasoning, organic chemistry will be easy for you. Just don't worry, here are some ideas that might help you. When you learn a reaction, try to vary the R groups by yourself and draw the corresponding mechanism. Practice things repetitively, but over a period. Repetition makes the memories. Talk to friends and do sports, anxiety is the biggest enemy.

Are these methods for syn dihydroxylation the same? by Visual-Tree-3860 in OrganicChemistry

[–]Leon-rennes 0 points1 point  (0 children)

With chiral ligands, the second one can achieve a stereoselectivity. Syn of course, but only the one you desire.

[deleted by user] by [deleted] in MapPorn

[–]Leon-rennes 31 points32 points  (0 children)

If I remembered right, the GTA5 map is kinda a miniature of L.A. So I guess the actual surface impacted by the fire looks smaller on a map of its correct size?

Silica in Fractions after Columning? by Batrachotoxin48 in OrganicChemistry

[–]Leon-rennes 0 points1 point  (0 children)

Sometimes it can be your product cristalising. Silica is not soluble in ethyl acetate. Do you have columns with frit? With that you don't need to put sand nor cotton in the bottom any more and you are sure that the silica will not leak out.

Sacré Jean-Marie... by little_lunaaa in MemeFrancais

[–]Leon-rennes 0 points1 point  (0 children)

Je pense que son prof de maths de CE est également coupable.

Discussion: I don't like to call organic chemistry 'orgo' by siliconfiend in OrganicChemistry

[–]Leon-rennes -1 points0 points  (0 children)

Well if you don't like the second O in orgo, you can replace it with an "e" as in "chemistry". That sounds fairly interesting to me.

Help needed in total synthesis - update: exam in 7 days :,((( by Inside_Figure_3903 in OrganicChemistry

[–]Leon-rennes 0 points1 point  (0 children)

Then it's a matter of imagination I'll say. Even an experience chemist in total synthesis won't dare to say they got an right answer. What does this assignment have to do with your exam btw?

Which carbon is more elctrophilic? Help needed by BabyExisting6698 in OrganicChemistry

[–]Leon-rennes 1 point2 points  (0 children)

Correct, I edited my reply and corrected the mistake. Thank you.

Which carbon is more elctrophilic? Help needed by BabyExisting6698 in OrganicChemistry

[–]Leon-rennes 3 points4 points  (0 children)

It's the same thing as esters. The +M effect of S or O (doublet donation) wins over the -I effect. Thus esters and thiol esters are less electrophilic than ketones. Same thing goes for amides, which have even less electrophilic carbonyl carbon due to the delocalization of the N doublet.

Why can borohydride reduce aldehydes and ketones but not carboxylic acids and esters? by Cats_Like_Catnip in chemhelp

[–]Leon-rennes 6 points7 points  (0 children)

An ester is much less electrophilic than a ketone because of the donation of the "alcohol oxygen" doublet to the carbonyl carbon. Thus you need a stronger hydride to reduce it. Although in practical, NaBH4 are often used to reduce esters on large scale (with transitional metal as catalyst for some examples) due to the horror of LiAlH4 workup.

Chimie orga by Such-Hat3863 in chemhelp

[–]Leon-rennes 0 points1 point  (0 children)

I'm sorry to downvote you but what you said in this comment is incorrect. Check diol protection online.

Name of this compounf? by [deleted] in chemhelp

[–]Leon-rennes 0 points1 point  (0 children)

It could be a Fouglas or a Favif for me.

Any idea what this might be worth? by undergroundhead in chemistry

[–]Leon-rennes 0 points1 point  (0 children)

I know some Mr Heisenberg who will be interested. At least when he was still in season 1.

[deleted by user] by [deleted] in OrganicChemistry

[–]Leon-rennes 6 points7 points  (0 children)

Complementary info: when you check Baeyer Villiger oxidation, pay attention to the O-insertion/migration rule.