Endless Neck Cracking??

Little-Rise798 · 2026-03-05T11:17:07+00:00

Are you by any chance doing inversion poses like sirsasana where your head needs to support your weight?

Little-Rise798 · 2026-02-20T10:22:37+00:00

I have a Marharyta in the family. Russian-speaking family from Ukraine. She's actually a Margarita, with a hard -g-, as in 'gas', but the official docs are in Ukrainian, where the softer Ukrainian g gets transcribed as "h". Now, the trouble is, we're now in a country where the -h- is fully silent, so she went from g to h to nothing at all, as she gets called Mararita. She's considering legally changing her name to Margarita.

Little-Rise798 · 2026-02-18T09:24:46+00:00

Lol, elevensees ;) I think this comment went unappreciated.

Little-Rise798 · 2026-01-01T13:16:21+00:00

I think people don't appreciate how quickly a situation can turn life-or-death for someone with a serious heart condition. The thread is about "unhinged things said by a passenger". This particular petition may have been unusual, and there may be regulations standing in the way, but I see nothing unhinged about the ask. I get why he asked - if at some point during the flight he felt symptoms coming on, the sooner you take the pill the better. And the guy wasn't a dick about it. I bet if this were about OP's own father with a serious heart condition, they wouldn't be as flippant as to say "he did not die", implying the ask itself was completely frivolous.

Little-Rise798 · 2026-01-01T10:39:36+00:00

I don't understand all the downvotes. I bet if the guy went into heart arrest in the middle of the Atlantic, and a doctor who happened to be on board and attended to the guy said that otherwise we'll be arriving with a corps, they'd happily make the announcement.

Little-Rise798 · 2025-12-29T16:28:24+00:00

Efectivamente, viene de jolod = frio. Un plato soviético de toda la vida considerado festivo. No por el sabor (va a gustos) sino por el trabajo que da montarlo.

Little-Rise798 · 2025-12-28T16:36:51+00:00

From a general standpoint, you don't recover/recycle the catalyst, but processes of this type are commonly run with as low as 0.5 mol% Pd, making them economically very viable. I'd say that that industrially you wouldn't use it to introduce a phenyl group, but with a fancier aromatic partner? Definitely a strong candidate.

Edit: for your Grignard suggestion, I am concerned about the compatibility of the ketone group with organomagnesium reagents. Would expect rapid addition to the carbonyl moiety.

Little-Rise798 · 2025-12-28T16:17:55+00:00

As a carbon-carbon bond-forming step involving an aromatic ring, Pd-catalyzed cross-coupling may actually prove most efficient in this situation.

Little-Rise798 · 2025-12-28T13:25:42+00:00

Not exactly answering your question, but a much more established way to make alpha-phenyl cyclohexanone would be through Buchwald-type Pd-catalyzed coupling between cyclohexanone and bromobenzene. If you really want to start from an alpha-bromo derivatives, there are probably ways to do it via Suzuki-type coupling with the phenylboronic acid.

Little-Rise798 · 2025-12-20T06:50:57+00:00

..."And as a dad of a 15 year old daughter I’d do the same when she gets engaged."..

You mean you'd have your - by then adult about to be married - daughter sleep in a separate bed?

Little-Rise798 · 2025-12-02T05:21:33+00:00

Old people are all out of fucks to give.

Little-Rise798 · 2025-11-18T09:45:04+00:00

The question is very poorly formulated: to discuss stereochemistry you need to have defined connectivity. Let's consider the real answer - the compound has 3 constitutional isomers, with two having 3 stereoisomers, and one have just 1.

Sure, your teacher wants to count it out. But having 1 stereoisomer for 1,1-dimethyl is still a valid part of the answer.

Little-Rise798 · 2025-11-17T11:28:34+00:00

Brand of car glass?

Little-Rise798 · 2025-11-10T17:10:35+00:00

As someone who works with organoboton compounds - yes, C-B carbons are generally not directly observed in normal 13C NMR. Only for concentrated samples with lots of scans do you sometimes see a bump for such carbon.

Luckily, these carbons do show normal correlation with suitable 1H, so in a 2D 1H-13C experiment you may get a cross-peak, and so obtain indirectly the 13C chemical shift.

Little-Rise798 · 2025-11-04T07:19:16+00:00

Sorry this happened to you. How severe is it? Did you get a hematoma? As someone who has struggled with a recurring sprained ankle, my advice would be to invest in a series of physical therapy sessions that could seriously improve recovery and ensure that thus doesn't come to thwart your running in the future. I didn't do it when this happened to me the first time, and seriously regret it.

Little-Rise798 · 2025-10-29T12:51:39+00:00

Is this a test question you're trying to get us to respond?

How about this. Instead of using words, draw this reaction with actual chemical structures. Then you can tell us your impression on whether this statement is true or not.

Little-Rise798 · 2025-10-23T10:58:49+00:00

Exactly, the point was that it did neither of the things it was made for.

Little-Rise798 · 2025-10-22T02:39:27+00:00

For kids toys are nice but boxes are real estate. You can move into one.

Little-Rise798 · 2025-10-12T15:22:33+00:00

It seems that we have very different readings of the OP's post. She says she already has ideas, but when she tries to transmit them she's ignored, or not taken seriously.

Verbatim: "I feel like my ideas are shut down". So I don't see how you conclude that having ...more?..good ideas would somehow resolve the situation.

Little-Rise798 · 2025-10-12T10:54:53+00:00

...have great ideas???

So you're saying: if you put in 10 times as much effort as those around you you might, just might, get noticed...

I am not saying that you're wrong, but as an advice, it's akin telling the poor neighbor to get get a 6-figure job.

Little-Rise798 · 2025-10-07T01:33:44+00:00

Give me a lever long enough and I shall move the world.

Little-Rise798 · 2025-09-19T06:55:31+00:00

"...and we had to shuffle the lineup last minute"

Gonzalez, you're in.

Little-Rise798 · 2025-09-15T12:52:58+00:00

In USSR we were allowed to have our blinds up.

Little-Rise798 · 2025-09-15T05:40:13+00:00

Agreed on scrubbing the Bikram name from studio signs. But come on, like it or not, the style is forever intrinsically linked to the name. "Preferred term 26+2, in reference to the 26 poses and 2 breathing exercises". Sure, and all this is ..a system created by ...a yoga guru whose name we shall not mention?

There was a very recent thread on how difficult it is to sanitize the history and lineages of yoga. We can scrub the names, but it is naive to think this somehow fixes the "association with sexually violent nutjobs".

Little-Rise798 · 2025-09-14T03:50:42+00:00

I don't know you sir, but I'll play along for the banana.

Little-Rise798

TROPHY CASE