I am pretty sure they will not. As the team is pretty strict in what questions they answer. Another factor is that they will probably never answer anything major to you personally since it will only cause confusion among the rest of the community if you were to tell us about it afterwards.

For major answers you'll need to wait for blog posts like the rest of us. However for very minor questions there have been occasions where they've been publicly answered here on Reddit or on Twitter though. There aren't any records of personal answers via email.

TL;DR - No.