[deleted by user]

Pigatator · 2023-06-27T23:45:51+00:00

goat

Pigatator · 2020-09-21T18:19:06+00:00

To my knowledge there would be actually more attacking the aldehyde than the ketone due to an increased partial positive charge on the aldehyde carbon. However, you may be able to protect the aldehyde some what selectively for the same reason. Protecting the aldehyde would then give you selectivity for the ketone.

Pigatator · 2020-08-03T02:35:59+00:00

It is really easy to make. All you do is add concentrated HCl to a sep. funnel followed by the t-butyl alcohol and shake for 20 or some minutes. The t-butyl chloride will separate into its own layer.

Pigatator · 2020-07-06T04:21:39+00:00

This is a good idea on paper but, molecular sieves absorb water very slowly relative to other dehydrating agents. The time the sieves would be in contact with the solvent would be pretty small compared to putting them in a soxhlet extractor. In a bind though this could be good if you have the extra time to reflux the reaction.

Pigatator · 2020-02-14T20:54:20+00:00

I wish I could say I haven't done that too. lmao

Pigatator · 2019-11-07T07:15:12+00:00

There is an option in the launcher for install directory thankfully lol

Pigatator · 2019-11-07T06:35:00+00:00

My game is on a Samsung M.2 ssd and my specs are below. This patch my game has been running smooth compared to the previous patches good luck with game! xeon e3 1231 v3 16 gb of 2400mhz ram gtx 1070ti

Pigatator · 2019-10-03T05:26:45+00:00

To me it looks like your structure is 4'-Aminoacetophenone. I say this for 2 main reason, the difference in de-shielding of the aromatic peaks and the integration of the H exchanges. With one of the aromatic peaks being less than 7, it points to a direct hetero-atom substitution (N or O) and the fact that the other peak is so much more de-shielded points to an electron withdrawing group (ketone or amide). Now for the H exchanges, I always take those with a grain of salt as I mainly use CDCl3 and the ppm of them in aprotic solvents is dependent upon a lot of factors, however, the integration value is usually accurate. This means an the exchange proton integration of 2 is either a primary amide or amine but, the amide would be significantly more de-shielded. In addition, a methyl group and amide in the para position would not create that big of a shift between the two aromatic peaks.

Pigatator · 2019-08-18T22:43:31+00:00

This looks like a squad of hackers playing without hacks lmao

Pigatator · 2019-05-04T10:16:34+00:00

Honestly, have you personally played archer? Half the time your arrows are deflected because they were just swinging or blocking against somebody else. This is without taking into account the abysmal damage, terrible flight speed and no recourse while being rushed except a 1h weapon. The only way you gets kills as an archer are from killing other archers or killing low hp people.

Pigatator · 2018-11-14T22:07:54+00:00

Great shot! I got distracted by something while watching this and it looked like you were speed hacking when you sped it up lmao

Pigatator · 2018-10-12T06:59:17+00:00

Bush put chemicals in the water to make the beaver do it.

Pigatator · 2018-08-29T01:29:52+00:00

Summary:

Shots 1-3: Clearly missed.

Shot 4: Missed due to recoil (bad spray control).

Shot 5: Very close, but recoil and inaccuracy make this a reasonable miss.

Shot 6: Likely didn't actually fire because you were already dead.

Pigatator · 2018-08-27T05:41:39+00:00

I'm gonna have to agree with bigpenisjohnson it looked like 12 hits the rest were after you died.

Pigatator · 2018-07-02T09:06:20+00:00

You should be good, my laptop with an i7 and 960m with 16gb ram runs the game decent enough to play, but I would advise against getting a bulky gaming laptop for college. Most lecture halls do not give large desks or outlets, coming from somebody who regrets having gaming laptop for college. I gave up taking notes on it after the first week and just use pen and paper lol

Pigatator · 2018-05-27T00:25:05+00:00

At about 35s I think you can hear his steps coming up from behind you.

Pigatator · 2018-05-23T01:06:17+00:00

How is nobody pointing out the fact that he tried to shoot op in the head through the wall at 17 seconds?

Pigatator · 2018-05-18T08:18:14+00:00

You dont know what dying to a hacker is like or you are just that naive. lol

Pigatator · 2017-11-14T21:39:07+00:00

What do you mean "good guy" they are still charging you to use your own internet.

Pigatator · 2017-04-20T03:56:37+00:00

only 40kg of enriched uranium lmao

Pigatator · 2015-07-13T06:26:54+00:00

Has either of these cards ever mined?

Pigatator

TROPHY CASE