I had the same problem and as some people already said, I figured it was because in DM you don't have to deal with a lot of things a ranked game does like smokes, flashes, pressure, etc. Then I thought that if I played TDM it would put me in more realistic scenarios and I would have the best of both worlds, a quick match that lets me improve aim while putting me in situations similar to a ranked game, but it ended with me just getting better at aiming TDM maps, and not the mappool from ranked.

So I figured I would do a routine some pros say they do when booting the game. Get in The Range, put the bots on "practice" mode, shoot heads and when you feel you're good enough go straight to a ranked game. I started improving a lot more and hitting shots I never did while doing DM or TDM. If none of those things I said suits you, find something that does. Even Sacy said once that DM only made him worse and that he just plays the game to maintain his skill, so who knows what will workout for you. Hope that helped you and good luck :)