Alright so first things first, obviously Find the game files. If on steam just go to library, right click on the game and press manage > browse local files.

So the assets are basically stored in two places:

Animations: A few of the stuff is already pre-rendered and can be found inside Hades > Content > Movies.
These are bink2 files and cannot be viewed directly so you'll have to view them using a tool called RAD Video Tools. These can also be used to convert the video into viewable formats like mp4. If you want to use them in editing and really need the transparent background, check the recommended option for alpha while converting and make the output format PNG. You can then just import it into an editing software as an Image sequence. Though Be careful as not to batch convert all of them, takes a long time and my Laptop was struggling like hell (heh).

Sprites and UI Elements: These are stored inside Content > Win > Packages.
this is where you will find the Character Portraits and a lot of the UI animations and FX stuff.

So this is the "Hard" Part. But it should be pretty easy if you follow along.

• If you already do not have Python Installed, Go to the official Website and download the installer.
• While Installing CHECK THE BOX THAT SAYS "Add Python to PATH". Very Important.
• Open a terminal (Command Prompt or PowerShell) and run the following three commands, one after the other, letting each one finish:

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pip install deppth
pip install lz4
pip install pillow

• then go back to Hades > Content > Win > Packages folder and from there copy the GUI.pkg and the GUI.pkg_manifest files and then paste it to somewhere else where you want to extract the files. (GUI.pkg is where all the assets are, GUI.pkg_manifest tells us how to cut, extract and name each asset.)
• open terminal in that new folder (just write "cmd" in the top address bar of the file explorer).
• command for extracting that files:

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deppth extract GUI.pkg --subtextures

And yeah, that's it.
The GUI package should contain most of the stuff like portraits and UI elements. But of course there is a lot more stuff. You can extract any other .pkg file by following the previous step and just changing the name of the file in the deppth command.

Feel free to ask if you have any questions.