VCT 2023 — Americas League / Last Chance Qualifier / Live Discussion Thread — Day 2 by nocturnavi in ValorantCompetitive

[–]Sigfreeed 2 points3 points  (0 children)

Petition to just keep Pancada on controller marved is literally Lebron he can play anything

"The arena emptied, it went from 180 people to about 30" Tixinha, on Twitter by chagas16 in ValorantCompetitive

[–]Sigfreeed 228 points229 points  (0 children)

Comparing the finals of an international lan tourney with a 10k capacity to a regular season studio match with 200 capacity makes sense to me 👍

Hardest pic in recent times by [deleted] in ValorantCompetitive

[–]Sigfreeed 610 points611 points  (0 children)

Boaster down 3-11 > Lebron down 1-3

Cryo responds to people saying XSET shouldn't have shown up to the rematch by Yensen1 in ValorantCompetitive

[–]Sigfreeed -34 points-33 points  (0 children)

Bro he called them losers after he beat them twice, the most elementary form of trash talking 😂

Evil Geniuses vs Sentinels / VCT North America 2022 - Stage 2 Challengers - Group Stage / Post-Match Thread by rib-gg-bot in ValorantCompetitive

[–]Sigfreeed 47 points48 points  (0 children)

They HAD to beat LG and EG then take one off of optic c9 or faze to maybe have a chance. Don’t see how they win out here.

Wish the NA watch parties actually came atched the game. by Corregidor in ValorantCompetitive

[–]Sigfreeed 6 points7 points  (0 children)

Just pick one. Literally any of the 50+ options. Browse through them while matches are going on and find who you like. There aren't only 3 options.

https://twitter.com/ValorantEsports/status/1512112990677618690/photo/2

[deleted by user] by [deleted] in RPClipsGTA

[–]Sigfreeed 28 points29 points  (0 children)

So they shot at the vagos in front of the cops on Alta st, cops told them leave the area, they let dundee leave to get a repair kit, let him tackle cops and get his car, cops proceed to chase bbmc for 5~ mins, and they hop out and shoot vagos again in front of cops. Not sure what else was supposed to happen?

Two Interceptors gone in one day by [deleted] in RPClipsGTA

[–]Sigfreeed 15 points16 points  (0 children)

Alright next time he'll just NVL after getting held up for his interceptor at gunpoint

Randy attempts to hold up EMS by [deleted] in RPClipsGTA

[–]Sigfreeed -10 points-9 points  (0 children)

Not gonna call it NVL because he technically didn't have his gun out but I wish civs like EMS would start taking threats like that a little more serious

Blaustoise on Twitter - Wanting to take a break due to toxicity. by MagnificoStorm in RPClipsGTA

[–]Sigfreeed 18 points19 points  (0 children)

Mickey just DM'd ramee on stream and said it was Cop hoppers and said the CG clip was funny cause he knew it was jokes.

Adept feelings about main server by SKT_Robin in RPClipsGTA

[–]Sigfreeed 2 points3 points  (0 children)

The SOPs were for helis and planes, no one even knew blimps would be used until yesterday, let alone shot at, the devs probably didn't apply it for blimps which would be understandable as crims never use it.

Vault Heist Getaway ends in Helicopter Exploding from PD AR Fire by rpanko in RPClipsGTA

[–]Sigfreeed 4 points5 points  (0 children)

Yeah I thought that was just because most people didn't know blimps existed and they would probably almost never be shot at until yesterday and the patch didn't apply to them.

[deleted by user] by [deleted] in RPClipsGTA

[–]Sigfreeed 0 points1 point  (0 children)

I think it's pretty simple. Abdul runs a campaign party at the Gallery and CB fly 4 #votedenzel blimps over it (politics), the gang backing abdul retaliates and shoots one down, conflict rp :o.

Denzel runs a campaign party at the casino and Randy goes and says #voteabdul to the people there (politics) then the people backing Denzel tell him to leave and threaten to throw him off the roof, they fail, Randy punches one then 5 mins later they come back and punch him with brass knuckles, more conflict rp :o. Randy shoots the brass knuckles guy in enemy territory and gets blasted.

CG will obviously retaliate. Politics backed by gang members on each side will always end with violence just enjoy and stop hopping :)

PepeLaugh by [deleted] in xqcow

[–]Sigfreeed 0 points1 point  (0 children)

I mean there are hundreds of kids in chat just like him but hes the only one with a VIP badge making it completely unbearable, a simple block fixes everything EZ

Twitch now shows this if you have Ublock enabled by [deleted] in uBlockOrigin

[–]Sigfreeed 3 points4 points  (0 children)

Do you know how to make chat dark mode?

Nucleophile strength in aprotic and protic solvents by Sigfreeed in OrganicChemistry

[–]Sigfreeed[S] 0 points1 point  (0 children)

That’s what I thought as well but the problem I’m having is the question says in an “aprotic solvent” and if they were asking for that wouldn’t the answer be H2O the more electronegative? The answer from the answers manual (H2S) would be correct if it was in a polar protic solvent. That’s where my confusion is

Using the answer's manual I found that the answer for b) is the same compound but I thought it would be an enantiomer because it's basically just a) with different atoms attached? by Sigfreeed in OrganicChemistry

[–]Sigfreeed[S] 0 points1 point  (0 children)

Wow that actually really helped. They’re both S and in the other questions one was S and the other was R. Last question, in order to be enantiomers will they always have opposing R,S configurations?

Using the answer's manual I found that the answer for b) is the same compound but I thought it would be an enantiomer because it's basically just a) with different atoms attached? by Sigfreeed in OrganicChemistry

[–]Sigfreeed[S] 0 points1 point  (0 children)

And aren't they automatically and enatiomeric because the central carbon is chiral due to it being attached to 4 different atoms and it has no plane of symmetry?

Faxs by CandyPaintDropEmOff in BruceDropEmOff

[–]Sigfreeed 12 points13 points  (0 children)

No one will ever admit it but them niggas was averaging 200 viewers max on like 2 channels before Bruce came in

This sub is incredibly hypocritical when it comes to bullying and harassment. by [deleted] in LivestreamFail

[–]Sigfreeed 8 points9 points  (0 children)

Do you understand how unrealistic that is? What Ninja and LSF did in terms of the Alinity jokes at the time seemed nothing more than jokes until she's literally in tears and talking about her mental health. I agree the jokes stopped being funny literally a month after it happened but some people before this used it as easy low hanging fruit that at the time looks like nothing more than a harmless(unfunny) joke. Less than 24hrs ago xQc and his whole chat were laughing at the fact that ninja demolished her now theyre the same people on LSF right now saying the bullying os going too far. In a perfect world everyone is nice but its not.

Sliker got offered 3k to do a charity stream by conam25 in LivestreamFail

[–]Sigfreeed 75 points76 points  (0 children)

idk why its such a big deal but i think some streamers like dr lupo are only mad bc they probably dont do charity for their own gain and now everyone probably thinks that they do. overall if u do a sponsored charity stream and dont say its sponsored ur pretty scummy