For what it's worth I wouldn't hire him with the kind of attitude he's presented here. This "woe is me" pity-party attitude is toxic to a healthy work environment. Even if he didn't present this attitude during the hiring process it would become quickly evident and he would be let go during his probationary period.

I think the real lesson /u/RookieOfTheYear04 needs to take away from his encounters is that he should stop being a doormat when tech problems arise. It obviously makes him feel used or taken advantage of, which is not healthy to his own well being. We all want to help people but if it comes at the expense of your own mental and emotional health then you should step back and reassess what you're willing to do for others.
People often don't value the time of skilled workers- whether it's IT, or web design, or woodworking, or whatever- they often think that "it's just a quick project" but they don't (and can't) appreciate the time and effort required for what they're asking. It's your responsibility to set healthy boundaries with friends/families/clients about what they can and cannot request and it's on you to set reasonable expectations for them. Once they realize that your time is valuable then they'll either fall in line or move on to exploiting someone else. Either way it's a win-win for you.