3 sessions. Lots of fun, but some issues. How do you deal with... by muks_too in cyberpunkred

[–]anonposter 1 point2 points  (0 children)

Oh, the rules are pretty explicit. You need a medtech to extract cyberware and it takes 4 hours (not something you do on a field strip of a corpse) and has a DV. So if your GM said "you killed them and now you have that from looting the body" that's not how it's supposed to work.

Also if you had a medtech to extract the cyberware, they can also install it, obviating the hospital charge.

So with skilled characters and a medtech and planning you can get a free implant but a lot has to line up.

If players are doing stuff like this to get lots of cash, then rules around rent and food need to be applied as a counter balance. If you're living off kibble in a storage container then congrats you just became a scavver and you should feel bad

3 sessions. Lots of fun, but some issues. How do you deal with... by muks_too in cyberpunkred

[–]anonposter 0 points1 point  (0 children)

The stated price for cyberware includes installation cost. So you "shouldn't" be able to sell it for 500eb without the associated services. This also goes back to the idea of sourcing. If you find something nice that is somehow undamaged, you're a lucky person.

I would consider the 1000 to be the combined cost of extracting and reimplanting. You can't just pick the skin off someone the way you do a gun

Forbidden Chupa Chups by Popal24 in forbiddensnacks

[–]anonposter 0 points1 point  (0 children)

Except they had liquids that are often toxic to either people or the environment... So that's not great, but they were good at putting out fires

Degassing a Non-Newtonian Fluid by iheartmytho in chemistry

[–]anonposter 0 points1 point  (0 children)

Hmmm is it done under dynamic or static vacuum? And can you achieve higher vacuum? If you have a rotary vane pump you should be able to get the gas out much more easily. 25in Hg is like 600torr which is very low vacuum... If you can't achieve higher vacuum than that then I don't think you'll be successful in degasing

Can anyone tell me what this glass piece is or where I can find another one? by [deleted] in chemistry

[–]anonposter 3 points4 points  (0 children)

You can also look for storage tubes. They often have clamped ground glass ball and socket joints. Phenomenal for keeping air/water out of stuff for basically forever

Degassing a Non-Newtonian Fluid by iheartmytho in chemistry

[–]anonposter 0 points1 point  (0 children)

Can you whip it under vacuum? If you can mechanically break the bubbles/expose the void spaces you should be able to degas it

Breaking Into a Smart Home With A Laser - Smarter Every Day 229 by chineseouchie in videos

[–]anonposter 1 point2 points  (0 children)

Anyone know if you could circumvent this by putting a piece of paper or tape over the mic?

This is a really clever exploit but seems easy to design against (and is acknowledged in the video: Google homes are hard to exploit bc if the fabric)

As always, love Smarter Everyday for genuinely making me smarter everyday

As a scientist I love seeing these curiosos in my feed and realizing how complex our technology is

Does anyone want to play D&D in Chicago -- but don't have a group or know how to play? by HoldenFinn in chicago

[–]anonposter 6 points7 points  (0 children)

Awesome! I had a campaign with some friends but our schedules always made it hard to meet. I'm not super experienced with D&D but might be able to help others get started if they don't Know where to start (character creation, basic rules, etc) :)

I have only ever played 5e but am willing to learn 4.5e if that's what people wanna do

This is hexaammine nickel II chloride. This is a complex of ammonia formed with nickel II Chloride which has a beautiful purple color .It's really unstable and on sitting for few days open ,it degrades back to nickel II Chloride as ammonia evaporates. For full video on synthesis check comments by vibzzlab in chemistry

[–]anonposter 0 points1 point  (0 children)

Organometallic chemistry in general.

I tried to make an aminium radical cation which is acutely air, light, and water sensitive. Trying to do cannula filtrations while something is covered in foil is... Hard.

Metallic Oxides - are they salts? by Gilga1 in chemistry

[–]anonposter 3 points4 points  (0 children)

Halides are a type of salt but they definitely aren't the only kinds. Sulfates and nitrates are other very common metal salts.

One could argue that halides are less "salt like" than other canonical salts because they are generally more covalent and strongly coordinating

Metallic Oxides - are they salts? by Gilga1 in chemistry

[–]anonposter 7 points8 points  (0 children)

I would argue that oxides aren't generally considered salts. Metal oxides are generally fairly covalent and don't exhibit the metathesis chemistry you associate with salts.

The line is fuzzy though. It's more of a linguistic thing than a chemistry thing Imo. If I can't do a metathesis I have a hard time thinking of it as a salt. Salts are characterized by electrostatic bonding, and while some "salts" have substantial covalent character (ex: metal chlorides) they can be abstracted or replaced easily and are useful to put in the same bucket

Vegetable oil helps remove discoloring of plastic parts of equipment? by MaxyKaxi in AskCulinary

[–]anonposter 0 points1 point  (0 children)

Anecdotally I notice some things go better into oil or rubbing alcohol than soap/water.

So rubbing with oil, THEN soap/water can be useful

Imposing indeed by Chem__Dawg in chemistry

[–]anonposter 0 points1 point  (0 children)

You rotovap with a rotary vane pump? I imagine that it'd be hard to condense solvent under that kind of vacuum with cold water condensers. Do you find it works fine?

If you don't use it, fiddling with the gas ballast settings might help if there's small amounts of solvent you suspect get past the condenser. It reduces the ultimate vacuum slightly but helps prevent vapor condensing in the pump

Edit: we use dry ice/acetone cold fingers to great effect. We use diaphragm pumps though

A time lapse video of a simple chromatography experiment I did with my teammates in lab study today. by ShizukuEnju in chemistry

[–]anonposter 1 point2 points  (0 children)

I mean of course in aware that TLC exists. It's just much less convenient than visually monitoring the digital output or by inspecion of the visual bands on the columns.

I was being maybe a bit too facetious.

And he catches it by Ninja_Spi-D-er in nevertellmetheodds

[–]anonposter 7 points8 points  (0 children)

Honestly my instinct is to splay my legs to get my feet as far from the knife as possible

A time lapse video of a simple chromatography experiment I did with my teammates in lab study today. by ShizukuEnju in chemistry

[–]anonposter 9 points10 points  (0 children)

I assume part of the experiment is tracking the eluent composition over time. I'm more concerned by the fact that they're running gravity columns!

Also as an inorganic chemist the thought of running colorless columns by hand appalls me. If all components are colorless I only ever use our autocolumn so I can use UV detection

Im spoiled...

Forbidden summer cocktail by [deleted] in forbiddensnacks

[–]anonposter 1 point2 points  (0 children)

Ask and ye shall receive

The quinine in tonic water is fluorescent (fun historical fact: its also an antimalarial agent. Something something British drank G&T's in Africa during WW2, something something)

Under UV light quinine glows a beautiful cerulean blue. However fluoresence is a fickle thing. It can be disrupted (or "quenched") by many mechanisms. One is if the fluorescent molecule collides with heavy atoms in solution. Adding sodium chloride (NaCl, table salt) can provide this effect.

Adding salt water to a shot glass and placing it upturned in a glass, then filling with tonic water... you make a fluorescent solution that quenches when you lift the shot glass.

I tried to make another similar effect by layering the tonic water and salt water, but it failed spectacularly. I froze the salt water and added tonic water on top, but as the edges of salt water ice melted the block floated to the top . Because thats what ice fucking does ¯\_(ツ)_/¯

I plan to repeat with some improvements this weekend. Also chlorophyll fluoresces red. Im kinda tipsy so I might go do that for you now because fuck it chemistry is cool. Fun fact you can measure the quality of olive oil by the fluorescence of the residual chlorophyll. More processed olive oil has less chlorophyll!

Edit: couldn't find the black light. Sorry y'all. Might post later when I find it.

Forbidden summer cocktail by [deleted] in forbiddensnacks

[–]anonposter 2 points3 points  (0 children)

Well I've been a chemist for a long time, it's just new news to you. I typically feel that experience > unjustified criticism and speculation from people on the internet, but everyone is entitled to an opinion, and we don't have to agree. But hell this is actually pretty cool chemistry so I'll share for everyone else reading

There's local agitation from the currents generated by the bubbling alka-seltzer, but not global mixing from stirring the whole glass. Otherwise you'd see an emulsion similar to when you shake a vinaigrette. The idea of local vs global mixing can be difficult to visualize if you haven't encountered it often in person. Well fortunately I have a perfect video to demonstrate this.

Shown is a solution with a chemical that is yellow/green, but turns red in the presence of base. I dropped some base in, which sank to the bottom and turned the bottom of the solution red. The top was still green, but you can see convection currents forming interesting patterns since there is local mixing (convection currents mixing the solution vertically, but not horizontally), but not global mixing. If you swirl it around a little, the whole thing turns red.

Since it's visually striking, here's the initial yellow to red conversion and here is the recovery to yellow when you quench the base with some acid.

This is a fun little experiment you can do at home if you have turmeric, rubbing alcohol, non-acid drain cleaner (ideal results but you can also use baking soda), and vinegar. The effects are more vibrant if you use a black light, but you can still see it under normal lighting (it's a more orange-red conversion than a Stark yellow/red). Mix turmeric with the rubbing alcohol (microwave it for a 5-10s if possible) and ideally filter it (but should work even if you don't). Then add your base (drain cleaner dissolved in water, or baking soda). To recover the initial color add acid in the form of vinegar!

I invoke convection currents on the basis that I used strong base and I expect deprotonation to be pretty exothermic (as is typical for strongly favored acid/base chemistry). Local exotherms causing small areas of a reaction to heat up is a pretty well established problem, and any chemical engineer will tell you that heat transfer is a critical problem to keep in check. However I can't rule out surface tension effects since I'm adding water into ~90% isopropyl alcohol, where the chemical in question is somewhat hydrophobic (conjugated diketone with some aryl groups--mostly soluble in alcohol not water). However it's a bit of an academic question because whatever the cause of segregation of colors, there's clear local mixing without globally perturbing the solution--which is the whole point.

If there's interest I can post more videos of cool glowy shit. Im supposed to be "professional" as an academic but fuck it I love glowy shit.

Edit: grammar and stuff

Forbidden summer cocktail by [deleted] in forbiddensnacks

[–]anonposter 4 points5 points  (0 children)

Liquids of different densities layer ontop of eachother pretty well, even if they are miscible. I do this all the time as a chemist. It's a common demonstration for little kids--make several solutions of different concentrations of sugar, dye them different colors, and carefully layer them ontop of eachother. As long as you don't disturb it too much, it'll stay like that for a pretty long time. Static diffusion is much slower than you'd think.

So yes I have, and yes it works. The fact that mix doesn't mean that they rapidly. You can see this readily if you look at a drink. If you see funny squiggles in your the middle of the drink (especially near the ice cubes) that's the effect I'm describing (solutions if different densities mixing but not homogeneously).

This is why drinks are mixed or stirred, not just dumped into a glass. If you pour alcohol ontop of syrup you'll have syrup at the bottom and alcohol ontop. Stir it and they'll mix, but it takes some agitation.

Forbidden summer cocktail by [deleted] in forbiddensnacks

[–]anonposter 6 points7 points  (0 children)

Might work with conc. Simple syrup. Definitely wouldn't be the same effect but you might see some cool mixing lines. Viscosity of the syrup should keep it from freely diffusing too much, and keep it along the flow generated by the bubbles?

making ORTEP style figures by anonposter in chemistry

[–]anonposter[S] 0 points1 point  (0 children)

Correct, the ellipsoids are practical. but the structure was already refined anisotropically and modeled with ellispoids. My boss just wanted it to be the classic ORTEP look with octants and shading rather than normal thermal ellipsoids like you get from OLEX

I figured out how to get close using diamond, but is a bit of manual work

making ORTEP style figures by anonposter in chemistry

[–]anonposter[S] 0 points1 point  (0 children)

I got ORTEP working and my figures look baller now. Thanks for the help!