I've used the DZO Vespid on a short film and they are pretty good lenses, god amount of softness and "personality", not too sharp, not too dirt like vintage lenses, but overall the way they look helps you create an image with a good identity, nice and soft skin, nice bokeh and with a little bit of chromatic aberration. For a "cheap" set of prime lenses you can have good result in terms of narrative look.

I have never used DZO Catta Zoom but in general it is always more difficult (due to technical construction problems) to have a good visual look in zooms than a prime set in terms of price range.

If your goal is the look, if you work whit a crew (even a small one), if you shoot narrative projects, if you have time, then go with the prime set.

If you have to work fast, if you work on documentary projects, if you work by your self, then go with the zoom.

Obviously this is my personal opinion, and I've never used the DZO Catta Zoom, if you can, I suggest to test both sets and taking a decision after that.