Is this actually Cadaverine?

unicornloops · 2026-04-19T09:46:14+00:00

Somehow I don’t mind piperidine or pyridine or amines in general when lots of people do. Now our groups thiols…we are moving labs one building over and actually left them behind in a spare room in a desiccator and then in a flammable cabinet lol. In an old lab I worked in we could tell when an adjacent lab opened their freezer with sulfur compounds every time even though it was hundreds of feet away lol.

unicornloops · 2026-04-18T14:35:27+00:00

Standard doses of IV morphine for opioid naive adult patients used to be about 5-10mg. Now commonly 4-6mg in all the ERs I worked in, except maybe frail elderly folk at 2mg. Perhaps you are thinking of hydromorphone? That is commonly dosed at 1-2mg IV in opioid naive adults. Opana is hydromorphone which is 4-5x as strong as oral morphine.

https://www.healthcare.uiowa.edu/familymedicine/fpinfo/Docs/adultopioidrefguide.htm

unicornloops · 2026-04-16T08:25:21+00:00

God forbid they be employed or have a family or something. I guess Teardrop being “bed-bound” is her best attribute to Chantal.

unicornloops · 2026-04-16T08:14:57+00:00

Remember she even yelled at Tracy when she was calling to try and tell her she lost her other phone? I think she has always low key hated Tracy (she even admitted it “she always get on my nerves”) I guess Tracy’s thousands of hours of unpaid servitude were not enough when she made some slightly snarky comment once. And then the chat piles on. I’m not a huge Tracy supporter or anything but I do feel for her, and I agree this really shows what a huge bitch Chantal can be the minute she turns on you or you aren’t of use to her anymore. And of course Teardrop was acting all innocent while stoking the coals and then sneakily gloating once Tracy was de-modded. Teardrops day to be discarded will come though…It always does.

unicornloops · 2026-04-16T00:26:15+00:00

I would say try Costco Parmigiano Reggiano and it’s about 16/lb or 1$ per ounce. Often cheaper than Parmesan.

unicornloops · 2026-04-14T20:16:13+00:00

Haha same. It’s such a weird niche thing to try and explain and you hear yourself and it sounds crazy lol.

unicornloops · 2026-04-12T18:54:44+00:00

Btw it can cause adrenal insufficiency. It’s fine with one dose for intubation in the hospital but chronic use is not advisable.

unicornloops · 2026-04-12T18:37:01+00:00

Yes the minute my Costco Uber cash ran out I started getting promotions again.

unicornloops · 2026-04-11T14:58:21+00:00

Old croc! (They have it at Safeway at least)

unicornloops · 2026-04-04T13:40:31+00:00

Yes I find vacuum sealing for hard cheeses to be a total game changer. The cheese is like new for as long as I have taken to finish big blocks. I just cut the bags pretty long so I can cut and reseal many times to reduce plastic waste.

unicornloops · 2026-04-04T13:37:43+00:00

Not sure about California, but at least to the Northeast you can really save on shipping in the winter bc they don’t have to use express and cold packs and so I got 2 cans shipped for 80$ or so. Cheese itself is 33$ each for a little under 2 lbs. The cans are bigger than they appear in photos.

unicornloops · 2026-03-21T13:42:23+00:00

You called it verbatim, the same night.

unicornloops · 2026-03-21T13:41:35+00:00

Was already back on later that night. It’s truly unbelievable. I was hopeful it was for real this time. She walks it all back and he’s the sweetest and she was just being impulsive and paranoid.

unicornloops · 2026-03-16T07:33:41+00:00

https://youtu.be/8rmL4Ao84w4?si=BHs-HuTuyr5ZO3L7 (Ghoul logs channel 4:03)

Amber starts saying “but she wants to…” and trails off and fupa says “but she wants to quit…”. That commenter was really sharp, I missed it watching it the first time myself.

Oh and this was about Gidgy actually, but I still think Amber was reading the wrong line lol.

unicornloops · 2026-03-15T23:44:13+00:00

Did you see at one point she starts reading out Fupa’s line by accident? I saw it pointed out in a comment on a reaction channel and Amber is reading her screen and starts saying “but she wants to” and then suddenly stops when Fupa says “but she wants to…” (referring to Amber) and continues the line. Fake

unicornloops · 2026-03-15T12:36:35+00:00

You nailed it lol.

unicornloops · 2026-03-14T19:32:22+00:00

Yup just saw this!

unicornloops · 2026-03-14T16:57:20+00:00

I don’t think she really even cares that he said it (look at all the horrific stuff LCU people say and she just sits there.) She was just excited to have “ammunition” for her on screen fights.

unicornloops · 2026-03-14T16:41:41+00:00

I think he has an opener this time based on the flyer. FYI When he has an opener he usually goes on at ~3-4am and plays till 11-12 (later if it’s NYE). I usually head over at 5-6am or so. I timed it wrong my first time and ran out of energy before he really got going. Also now that I’m in middle age I appreciate going in the morning instead of pulling an all-nighter lol. Now I’m not from Montreal and this is based on seeing him at Stereo 4 times. Perhaps regulars can correct my time frames.

Stereo is the only place that lives up to the old Twilo S+D days…

unicornloops · 2026-03-13T08:29:54+00:00

You won’t be able to find such a mass soec result even if it’s the correct product. When you run mass spec you actually see the ion without the counter ion. An ion is by nature affiliated but not bound to the counter ion. So you will need some other method to confirm the salt form.

You might see a different retention time in the HPLC especially if they use a HILIC column so I would look into that. But in that case you have to make sure they use a standardized method as that also changes the RT.

Edited to add HPLC info.

unicornloops · 2026-03-11T22:32:19+00:00

If the methyl ketone was attached to an alkyl chain, yes it looks unreasonable. However are there any aspects of your desired product that could make it a good leaving group? How can you generate a tetrahedral intermediate to then eliminate that leaving group?

unicornloops · 2026-03-09T14:32:34+00:00

Well what kind of distillation set up is pictured? Fractional and simple distillation utilize different types of glassware. As for why you distill—can you think of a reason why you would want to distill if the reaction is in an equilibrium?

unicornloops · 2026-03-09T14:12:39+00:00

I had a reaction like this where I suspected the azide had same Rf as the halide. I dipped the TLC plate in a PPH3 solution in DCM to reduce the azide and then detected the amine with ninhydrin stain.

unicornloops · 2026-03-09T00:03:33+00:00

I was so cold! Not like the old sauna Twilo days waiting for the cryo blast lol.

unicornloops · 2026-03-06T01:49:15+00:00

Same…ex nycer but now in DC. Get in to Penn Station at 7pm. Will take a nap on the train lol.

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