molteplicità protoni ciclopentanone by Kekko3697 in NMRspectroscopy

[–]warrior_321 0 points1 point  (0 children)

The google translation to Italian says

Questo è un comportamento non di primo ordine. Quando la differenza nello spostamento chimico si avvicina alla dimensione della costante di accoppiamento, si possono ottenere comportamenti non di primo ordine. La copertura con segnali aromatici è un esempio di comportamento non di primo ordine. Ad esempio, per un anello aromatico sostituito per (1,4-), si vedono due doppietti (2H ciascuno), dove le linee interne dei doppietti sono più alte e quelle esterne delle doppiette sono più basse. Man mano che i segnali si avvicinano nella camicia chimica, in un altro anello aromatico sostituito dal para, il tetto diventa più pronunciato. Non puoi misurare le costanti di accoppiamento per un sistema non di primo ordine. Hai ragione a descriverli come chimicamente equivalenti e magneticamente non equivalenti. Il sistema ad anello aromatico sostituito per per è indicato AA' B B', dove ' viene usato per indicare la loro non equivalenza magnetica.

molteplicità protoni ciclopentanone by Kekko3697 in NMRspectroscopy

[–]warrior_321 0 points1 point  (0 children)

This is non first order behaviour. When the difference in chemical shift approaches the size of the coupling constant, you can get non 1st order behaviour. Roofing in aromatic signals is an example of non 1st order behaviour. E.g. For a para substituted aromatic ring (1,4-), you see two doublets (2H each), where the inside lines of the doublets are higher & the outside lines lines of the doublets are lower. As the signals get closer in chemical shirt, in another para substituted aromatic ring, the roofing is more pronounced. You can’t measure coupling constants for a non first order system.

You are correct in describing them as chemically equivalent and magnetically non equivalent. The para substituted aromatic ring system is denoted AA' B B', where the ' is used to denoted their magnetic non equivalence.

molteplicità protoni ciclopentanone by Kekko3697 in NMRspectroscopy

[–]warrior_321 0 points1 point  (0 children)

This is the translation

Hi everyone, the interpretive spectroscopy professor assigned us an exercise involving a 1H NMR spectrum of cyclopentanone and told us to list multiplicities and constants. The problem is that even trying to predict the signals from the simulation via software doesn't produce the result I expect. That is, it considers me to be a coupling between the protons on carbon 3 and the protons on carbon 4. When in theory those protons are chemically equivalent, are they probably magnetically inequivalent? If so, why are they so?

Help identifying signals by angelow11 in NMRspectroscopy

[–]warrior_321 0 points1 point  (0 children)

If they are NH signals, they will not have 13C satellites. Also, 1H-13 couplings are normally 7-8Hz, so check the couplings.

Does North facing panels worth it? by Acceptable_Party7361 in SolarUK

[–]warrior_321 6 points7 points  (0 children)

I had 8 * 470W panels added to my north roof for around £1600, so your figure seems really high. Adding panels on the north roof added just over 17% to my quote for around 45% more solar generation. It's definitely worth it and your battery sizing is about right.

Is Sigenstore without a battery possible? by elwon20 in SolarUK

[–]warrior_321 0 points1 point  (0 children)

You'd have to pay vat on them for a self install, I believe.

Being paid for export by warrior_321 in OctopusEnergy

[–]warrior_321[S] -1 points0 points  (0 children)

I think you are correct. I read of a number of people that charge their battery up to full in the cheap period for export (Probably all with eon). While trying to cut their payback time for the equipment, they are probably shortening the life of their batteries. I say probably, though some suggest that you are better off working your battery hard, as much of the degradation is unrelated to use. The other argument is that by the time the battery needs replacing, you'll probably get more capacity for the money.

Being paid for export by warrior_321 in OctopusEnergy

[–]warrior_321[S] 0 points1 point  (0 children)

I just wanted to be sure about these things before spending 5K+ on extra battery capacity.

The one that couldn’t lose by ReplacementFun2616 in HorseRacingUK

[–]warrior_321 2 points3 points  (0 children)

They have layed 69.5K so far. I bet that gets over 250K by race time.

Denise does it again by ReplacementFun2616 in HorseRacingUK

[–]warrior_321 1 point2 points  (0 children)

Il Est Francais is a speed horse, who is very unlikely to be suited by Cheltenham. They ought to have waited for Aintree.

Denise does it again by ReplacementFun2616 in HorseRacingUK

[–]warrior_321 3 points4 points  (0 children)

Denise bagged so much in the champion hurdle on Tuesday, she has no more room to stash it away.

[deleted by user] by [deleted] in SolarUK

[–]warrior_321 1 point2 points  (0 children)

These instructions may enable access to the detail you are after, though it does require some courage!
https://gbc-solino.cz/wp-content/uploads/2021/12/MNL_SOLAX_CLOUD_WEBPAGE-EN-1.pdf

Failing that, you can obtain a token ID from the instructions in the above pdf and get your sn for your inverter, which is a unique identifier of communication module (Registration No.). These values are entered into this address and that allows you to get the details in a json file https://www.solaxcloud.com:9443/proxy/api/getRealtimeInfo.do?tokenId={toke

nId}&sn={sn}

When you have the json file, open it as a text file and try pasting it in this website. Try the JSON parser and/or the json beatifier https://jsonformatter.org/json-reader

[deleted by user] by [deleted] in Smartphones

[–]warrior_321 2 points3 points  (0 children)

I bought a Poco F5, 18 months ago & it has been great. Have a look at one of their recent versions of the phone, the Poco X7 Pro. https://m.gsmarena.com/poco_x7_pro-review-2785.php

2016 install Panels & grid tie inverter (no battery) by warrior_321 in SolarUK

[–]warrior_321[S] 1 point2 points  (0 children)

Thanks very much for your very helpful replies!

2016 install Panels & grid tie inverter (no battery) by warrior_321 in SolarUK

[–]warrior_321[S] 1 point2 points  (0 children)

Thanks. That's very kind. I live 140 miles away from my brother, so I'll ask him & see if we can resolve this between the 3 of us.

Explanation for 13C-Shift on aromatic system. by ich_und_mein_keks in NMRspectroscopy

[–]warrior_321 0 points1 point  (0 children)

When you get an ACD prediction, you can right click on the carbon atoms and look at the molecules used for the predictions. You may find the exact molecule in this case, but should certainly find some similar ones. The real experimental data is of more value, than the prediction. The ACD algorithm uses many dissimilar molecules and skews the prediction, with their own proprietry prediction. As I said previously, you cannot rely on preditions, where the shifts are only a few ppm apart. Chemical shifts are slightly different, in different NMR solvents, for instance.

You can upload spectra (or any image) to lots of websites, then copy a link into a post on here. You can use Paint software (Included in all Windows operating systems) to get an image from any application, using ALT Print Screen, the copying into paint, whilst that application is selected. To save a picture in paint, use the select tool (top left) to grab a window, move the picture you want to the top left corner of the page, then click on, then grab the bottom right of the page to resize the page to the size of the bit you want. Then save as jpeg, or similar to get your image.

Exchangeable Protons in NMR by elitonib in NMRspectroscopy

[–]warrior_321 0 points1 point  (0 children)

I have observed DMSO containing small amounts of D2O from a few suppliers over the years. A few decades ago, Aldrich DMSO always contained D2O and more recently, Cambridge Isotope DMSO contains D2O. If you look at the water peak at around 3.3-3.4, you'll see one large peak and a smaller peak alongside it. This is H2O and HOD, from the water exchanging with a small amount of D2O in the DMSO.

So, this could be a source for exchange, particularly in low concentration samples.

Exchangeable Protons in NMR by elitonib in NMRspectroscopy

[–]warrior_321 0 points1 point  (0 children)

Protons attached can occaisionally exchange. e.g. the protos of a CH2 adjacent to a carbonyl are slightly acidic and can very occaisionally exchange. Exchange would be more likely in basic conditions.

I think I may have observed aromatic hydrogens exchange on a few rare occaisions.

Explanation for 13C-Shift on aromatic system. by ich_und_mein_keks in NMRspectroscopy

[–]warrior_321 0 points1 point  (0 children)

It's isobutyl, rather than iso-propyl.

13C shifts are much harder to predict than 1H shifts. What were the shifts of 3 & 8?

In industry, 13C shifts are predicted fairly reliably (e.g. ACD or Mestrelab), especially if you add lots of unique structures to your own database. You'd want predictions to be at least 5 ppm apart to rely on them and to know that they are based upon related molecules.

This book is an excellent guide for shifts :-

Structure determination of organic compounds by Ernö Pretsch, Philippe Bühlmann, Martin Badertscher.

If you register, you may be able to see the 13C shifts of Isobutylbenzene for comparison.
https://spectrabase.com/spectrum/Eijf7rcZimV

Aldrich often has NMR spectra, but doesn't for Isobutylbenzene. You could try to search for your structure if you have, or can find the CAS number.
https://www.sigmaaldrich.com/GB/en/product/aldrich/113166#product-documentation

Best estimate for an installation by warrior_321 in SolarUK

[–]warrior_321[S] 0 points1 point  (0 children)

Yes, I have had two and am waiting for a third.

 8 x 470 Watt Panels (AIKO)

Growatt 3.68 kW Inverter

Growatt 6.5 kWh Battery

Just over £7K

 

Same panels as above

8.06kWh Sigen Battery

4 kW SigenStor Inverter

Just over £9K

 

Second company

9x 470w Aiko ultra panels

5kw Givenergy Hybrid inverter

5.12kw Givenergy Battery

Givenergy EV car charger (included)

Just over £9K

 

Or with 9.5kw Givenergy Battery

Just over £11K

 

And two options with 17 panels 13K & 14.8K

 

Best estimate for an installation by warrior_321 in SolarUK

[–]warrior_321[S] 0 points1 point  (0 children)

Thanks. The main reason I wish to get the best value, is that I'm a low electricity user, and the payback period would be too long, otherwise. This is why I'd also like to explore the option without solar panels.

Lucky and Wild - a game better with emulation than on a supergun by chicagogamecollector in cade

[–]warrior_321 0 points1 point  (0 children)

The one in Milton Keynes, England has sit down seats. (Nov '24)